388570-70-5

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 4683-45-8 3-methoxy-5,5-dimethyl-cyclohex-2-enone 

Downstream Products

• 388570-72-7 2-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-6-methoxy-benzaldehyde 
• 388570-78-3 2-(tert-butyl-diphenyl-silanyloxymethyl)-6-hydroxy-4-methoxy-benzaldehyde 
• 388570-73-8 2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-6-methoxy-benzaldehyde 
• 705-76-0 3,5-dimethoxybenzyl alcohol 
• 388570-83-0 2-(tert-butyl-diphenyl-silanyloxymethyl)-4,6-dimethoxy-benzaldehyde 
• 388570-85-2 tert-butyl-(2-[1,3]dithiolan-2-yl-3,5-dimethoxy-benzyloxy)-diphenyl-silane 
• 1017280-64-6 O₂N(Br)C₆H₃C₆H₂(OMe)(OH)SnPh₃ 

Relevant academic research and scientific papers

Synthesis of programmable tetra-ortho-substituted biaryl compounds using Diels-Alder cycloadditions/cycloreversions of disubstituted alkynyl stannanes

Orthogonally functionalized, programmable biaryl templates have been synthesized utilizing aryl acetylenic stannanes and oxygenated dienes in a cycloaddition/cycloreversion strategy. Sequential functionalization of each of the four ortho positions has bee

4-(Trialkylsilyl)oxybut-2-ynals as dienophiles in the Diels-Alder synthesis of α-(hydroxymethyl)benzaldehydes

The α-(hydroxymethyl)benzaldehyde derivative 2 has been synthesized by heating ynal 3 with diene 5, which produced the α-(silyloxymethyl)benzaldehyde 6 by a Diels-Alder/retro-Diels-Alder process, followed by methylation, thioacetalization, and removal of the silyl protecting group. Decarbonylation of α-(silyloxymethyl)benzaldehydes 6 and 10 takes place readily in the presence of zinc(II) chloride or para-toluenesulfonic acid.