38938-22-6

Upstream product

• 6591-07-7 diphenylphosphane sulfide 
• 109-89-7 diethylamine 
• 649-15-0 N,N-diethyl-4-methylbenzenesulfonamide 
• 15475-27-1 potassium diphenylphosphine 
• 1079-66-9 chloro-diphenylphosphine 
• 1015-37-8 diphenylthiophosphinoyl chloride 
• 19172-47-5 Lawessons reagent 
• 56372-47-5 N,N-diethyl P,P-diphenylphosphinamide 
• 1636-15-3 (diethylamino)diphenylphosphine 

Downstream Products

• 4559-70-0 Diphenylphosphine oxide 
• 829-85-6 diphenylphosphane 

Relevant academic research and scientific papers

Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides

A new regioselective synthetic methodology for benzo[b]phosphole derivatives has been developed. Thus, a range of functionalized benzo[b]phosphole oxides could be synthesized via Rh(III)-catalyzed C-H alkenylation of arylthiophosphinamides with alkynes fo

The reactivity of arylphosphorus acid amides under Birch reduction conditions

Several classes of arylphosphorus acid amides have been tested in reactions with alkali metal solutions in liquid ammonia. The outcomes of such reactions depend on the structures of the starting materials. Generally, two processes-Birch reduction or cleavage of the P-aryl bond-can be operative. Diarylphosphinic amides tend to undergo double Birch reduction to afford bis(cyclohexadienyl)phosphinic amides. Copyright

Nucleophilic substitution reaction at the nitrogen of arylsulfonamides with phosphide anion

A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.

An unexpected carbon dioxide insertion in the reaction of trans-2,4-disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, or trans-2,6-disubstituted piperidine with diphenylthiophosphinic chloride and diphenylselenophosphinic chloride

In the reaction of trans-2,4-disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, or trans2,6-disubstituted piperidine with diphenylthiophosphinic chloride or diphenylselenophosphinic chloride in acetonitrile in the presence of potassium carbonat

Reactivity of X3P compounds with elemental sulfur, carbon disulfide or both, to yield X3PS, X3RCS2 or X3P.Sn.CS2 adducts

Kinetic constants k2 have been obtained for the reaction of sulfur with 25 PIII compounds in toluene or hexane. In the series PhnMe3-nP (n = 1-3) or PhnBu3-nP (n = 0-3), log k2 decreases linearly with Σχi (χi=Tolman's electronic parameter of each ligand on P), taken as a gauge for the donor strength of P. Dramatic deviations from additivity are observed for the series PhnP(OEt)3-n, PhnP(OEt)3-n, and BunP(OEt)3-n(n = 0-3); the deviation is smaller for PhnPCl3-n, and even smaller for PhnP(NEt2)3-n . The results are discussed in terms of P-coordination (PIV vs. PV), stability and geometry of the intermediate X3P.S8 or of the transition state leading to this adduct, emphasis being laid on the donor/acceptor character of the P site. A similar dependence on X governs the reactivity of X3P with S8, CS2 or both, to give X3PS, X3P.CS2 (binary red adduct) or X3P.Sn.CS2 (ternary yellow adduct) respectively; an explanation for this parallelism is proposed.

Organic phosphorus compounds 106.1 a 31P-NMR study of phosphinous-, phosphinic-, and thiophosphinic amides

The synthesis, physical, chemical and spectroscopic properties of eight different types of phosphinous-, phosphinic-and thiophosphinic amides are reported. It is shown that the 31P-chem. shifts of tertiary amides are at lower magnetic field than that of secondary amides. As an exception, in the bis(tertiary butyl) series this trend is reversed.

Phosphororganische Verbindungen 100. Thiophosphylverbindungen Durch P=O/P=S-Austausch

Phosphinic-acid-, phosphonic-acid- and phosphoric-acid-derivatives react in high yields with Lawesson's reagent to form the corresponding thiophosphyl-compounds.