38938-55-5

Upstream product

• 18712-15-7 3-ethoxy-benzo[d]isothiazole 1,1-dioxide 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 81-07-2 saccharin 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 1166859-72-8 3-(4-methoxyphenyl)-1,2-benzisothiazoline 1,1-dioxide 
• 1009806-68-1 3-(4-methoxyphenyl)-2,3-dihydrobenzo[d]isothiazole–1,1-dioxide 
• 1259436-58-2 (R)-3-(4-methoxyphenyl)-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide 
• 1356266-12-0 (E)-ethyl 2-(8b-(4-methoxyphenyl)-4,4-dioxido-1H-azeto[1,2-b]benzo[d]isothiazol-2(8bH)-ylidene)acetate 
• 1356266-23-3 (E)-tert-butyl 2-(8b-(4-methoxyphenyl)-4,4-dioxido-1H-azeto[1,2-b]benzo[d]isothiazol-2(8bH)-ylidene)acetate 
• 1356266-35-7 tert-butyl 9b-(4-methoxyphenyl)-3,9b-dihydrobenzo[d]pyrrolo[1,2-b]isothiazole-1-carboxylate 5,5-dioxide 

Relevant academic research and scientific papers

B(C6F5)3-Catalyzed Reduction of Cyclic N-Sulfonyl Ketimines

A metal-free method for reduction of cyclic N-sulfonyl ketimines catalyzed by B(C6F5)3, using commercially available methylphenylsilane as a reducing reagent under mild conditions has been developed. This reductive protoco

Iridium(III)-Catalyzed Selective and Mild C-H Amidation of Cyclic N-Sulfonyl Ketimines with Organic Azides

A general protocol for iridium catalyzed direct C?H amidation of cyclic N-sulfonyl ketimines using sulfonyl, acyl and aryl azides as nitrogen source is reported herein. The reaction takes place at room temperature with acyl and aryl azides, while an elevated temperature needed with sulfonyl azides to furnish aminated sultams in excellent yields with complete chemo and regioselectivity, thus providing a robust and environmentally benign process to the synthesis of aminosultams. (Figure presented.).