389634-44-0

Basic information

• Product Name: (2R,3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol (R)-2-(1-hydroxybutyl)-3-furanylboronate
• CAS NO: 389634-44-0
• Molecular Weight: 602.535
• Mol File: 389634-44-0.mol

Chemical Properties

• CAS DataBase Reference: (2R,3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol (R)-2-(1-hydroxybutyl)-3-furanylboronate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol (R)-2-(1-hydroxybutyl)-3-furanylboronate(389634-44-0)
• EPA Substance Registry System: (2R,3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol (R)-2-(1-hydroxybutyl)-3-furanylboronate(389634-44-0)

Safety Data

• Hazardous Substances Data: 389634-44-0(Hazardous Substances Data)

Upstream product

• 927-77-5 n-propylmagnesium bromide 
• 389634-41-7 (4R,5R)-3-[4,5-bis(methoxydiphenyl-methyl)-1,3,2-dioxaborolan-2-yl]furan-2-carbaldehyde 
• 64817-17-0 3-bromo-2-hydroxymethylfuran 
• 938443-34-6 C₅H₅O₂B(OH)2 
• 389634-39-3 (2R,3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol 2-hydroxymethyl-3-furanylboronate 

Relevant articles and documents

Diastereoselective addition reactions of furyl aldehydes using chiral boronates as auxiliary: Application to the enantioselective synthesis of 2,3-disubstituted furyl alcohols

matrix presented The addition reactions of various nucleophiles to a furyl aldehyde bearing a chiral boronate at the C-3 position furnished chromatographically separable diastereomers. The R diastereoselection was more favorable when no additive was added