3926-11-2Relevant academic research and scientific papers
Reductive chlorination of bis(4-tertbutylphenyl)amine-N-oxyl nitroxyl radical
Golubev,Sen’
, p. 2074 - 2078 (2014/07/07)
Unlike cyclic aliphatic nitroxyls, whose oxidation with halogens gives oxoammonium salts, bis(4-tert-butylphenyl)amine-N-oxyl (1) treated with chlorine undergoes reductive chlorination to the corresponding di-and trichlorodiphenylamines. Chlorine partiall
Etude du Comportement Photochimique de quelques Diaryl-1,3-triazenes
Julliard, Michel,Vernin, Gaston,Metzger, Jacques
, p. 456 - 466 (2007/10/02)
The photolysis of Diaryl-1,3-triazenes gives products whose structures are consistent with a cage recombination process of homolytically formed radicals and subsequent abstraction of hydrogen from the solvent molecules by arylamino radicals.In aromatic solvents, a free-radical chain process leads to the formation of products resulting from the homolytic substitution on the solvent.Quenching experiments show that singlet and triplet excited states are reactive but that intersystem crossing efficiency is low.
