39274-34-5

Basic information

• Product Name: methyl cumenethiocarboxylate
• Synonyms: methyl cumenethiocarboxylate
• CAS NO: 39274-34-5
• Molecular Weight: 194.298
• Mol File: 39274-34-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl cumenethiocarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl cumenethiocarboxylate(39274-34-5)
• EPA Substance Registry System: methyl cumenethiocarboxylate(39274-34-5)

Safety Data

• Hazardous Substances Data: 39274-34-5(Hazardous Substances Data)

Upstream product

• 98-82-8 Isopropylbenzene 
• 18369-83-0 methyl thiochloroformate 
• 75626-81-2 C₂H₃OS⁽¹⁺⁾*F₆Sb^(1-) 

Downstream Products

• 536-66-3 p-isopropylbenzoic acid 

Relevant articles and documents

Aromatic Substitution. 46. Methyl (Ethyl) Thio(Dithio)carboxylation of Aromatics with S-Methyl (S-Ethyl) Thiocarboxonium and Dithiocarboxonium Fluoroantimonates

S-Methyl(S-ethyl)thio(dithio)carboxinium ions were prepared by reacting methyl(ethyl) fluoride-antimony pentafluoride with carbonyl sulfide (carbon disulfide) and studied with 1H and 13C NMR spectroscopy.The ions were subsequently used in the novel carboxylation reaction of arenes to S-methyl (S-ethyl) thio(dithio)benzoates.The method was also found to be adaptable to the carboxylation of polystyrene to poly(styrenecarboxylic acid) without degradation of the polymer backbone.