39489-70-8Relevant academic research and scientific papers
Enantioselective carbenoid insertion into phenolic O-H bonds with a chiral copper(I) imidazoindolephosphine complex
Osako, Takao,Panichakul, Duanghathai,Uozumi, Yasuhiro
, p. 194 - 197 (2012/02/16)
The enantioselective O-H carbenoid insertion reaction with a new chiral copper(I) imidazoindolephosphine complex has been developed. The chiral copper(I) complex catalyzed the insertion of carbenoids derived from α-diazopropionates into the O-H bonds of various phenol derivatives to give the corresponding α-aryloxypropionates with up to 91% ee.
