39511-34-7Relevant academic research and scientific papers
Indium-mediated reductive elimination of halohydrins
Cho, Sangwon,Kang, Soyeon,Keum, Gyochang,Kang, Soon Bang,Han, So-Yeop,Kim, Youseung
, p. 180 - 182 (2003)
Olefin formation has been successfully carried out by reductive elimination reactions of halohydrins with Pd(PPh3)4/In/InCl3 in aqueous media.
An easy access to styrenes: Trans aryl 1,3-, 1,4- and 1,5-dienes, and 1,3,5-trienes by Hiyama cross-coupling catalyzed by palladium nanoparticles
Chatterjee, Tanmay,Dey, Raju,Ranu, Brindaban C.
experimental part, p. 1103 - 1110 (2011/07/08)
A convenient and efficient procedure has been developed for the vinylation of aryl-, styrenyl-, cinnamyl- and dienyl-halides by a Pd(0) nanoparticle-catalyzed Hiyama cross-coupling to provide the corresponding dienes and trienes in high yields. The reaction does not require any ligand or co-catalyst, and is carried out using PdCl2 and tetrabutyl ammonium fluoride (TBAF) in THF. Pd nanoparticles are generated in situ and are the active catalytic species in this reaction. A wide range of functionalized styrenes, trans aryl 1,3-, 1,4- and 1,5- dienes, 1,2-, 1-3 and 1,4-bis(1,3-dienes), and 1,3,5-trienes can be obtained by this procedure. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2011.
A PALLADIUM MEDIATED REDUCTIVE CYCLIZATION
Trost, Barry M.,Pietrusiewicz, K. Michal
, p. 4039 - 4042 (2007/10/02)
α,ω-bis(Allylic acetates) undergo regioselective intramolecular reductive coupling with hexamethyldistannane catalyzed by Pd(0).
