39579-75-4Relevant academic research and scientific papers
Facile one-pot synthesis of α-bromoketones from olefins using bromide/bromate couple as a nonhazardous brominating agent
Patil, Rajendra D.,Joshi, Girdhar,Adimurthy, Subbarayappa,Ranu, Brindaban C.
experimental part, p. 2529 - 2532 (2009/09/06)
A new method for the preparation of α-bromoketones from olefins using bromide/bromate couple as a nonhazardous brominating agent has been developed. Several α-bromoketones were successfully prepared from a variety of olefins by this method. This procedure is an alternative to conventional molecular bromine.
OXIDATIVE HALOGENATION OF 1-DECENE UNDER THE ACTION OF THE K2S2O8-Hlg- SYSTEM IN AN AQUEOUS-ACIDIC MEDIUM
Gutsulyak, R. B.,Nikitchenko, V. S.,Serguchev, Yu. A.
, p. 877 - 880 (2007/10/02)
The oxidizing system peroxodisulfate-halide ion in water at low pH was found to be effective and selective in hydroxyhalogenation and halogenoxyperchloratization of 1-decene.A reaction mechanism is proposed, in which the halogenosulfate anion is the reactive species.
Micellar Effects upon Alkene Bromination. 2. The Role of Alkene Hydrophobicity
Cerichelli, Giorgio,Grande, Celeste,Luchetti, Luciana,Mancini, Giovanna
, p. 3025 - 3030 (2007/10/02)
Surface polarity of cettyltrimethylammonium bromide (CTAB) aqueous micelles was checked by use of as a probe the bromination reaction of a series of 1-alkenes and a water-soluble alkene, cis-4-cyclohexene-1,2-dicarboxylic acid dimethyl ester (I).There was
