3972-25-6

Basic information

• Product Name: 2-METHYL-2-PROPAN(OL-D)
• Synonyms: TERT-BUTAN-OL-D 98 PLUS ATOM % D;2-METHYL-2-PROPAN(OL-D) 99 ATOM % D;tert-Butanol-OD >99.5 Atom % D;2-Methyl-2-propan(ol-d), tert-Butanol-OD, tert-Butyl alcohol-d;TERT-BUTANOL-O-D, 98+ ATOM % D, FOR NMR;1,1-Dimethyl(O-2H)ethanol;2-[(2H)Hydroxy]-2-methylpropane;2-Methyl-(O-2H)-2-propanol
• CAS NO: 3972-25-6
• Molecular Formula: C₄H₁₀O
• Molecular Weight: 75.13
• EINECS: 223-597-1
• Mol File: 3972-25-6.mol
• Article Data: 17

Chemical Properties

• Melting Point: 23-26 °C(lit.)
• Boiling Point: 83 °C(lit.)
• Flash Point: 52 °F
• Appearance: /
• Density: 0.786 g/mL at 25 °C
• Vapor Pressure: 46mmHg at 25°C
• Refractive Index: n20/D 1.3847(lit.)
• Storage Temp.: Flammables area
• Solubility: Acetone, Chloroform (Slightly), Methanol (Slightly)
• Explosive Limit: 2.3-8.0%(V)
• CAS DataBase Reference: 2-METHYL-2-PROPAN(OL-D)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYL-2-PROPAN(OL-D)(3972-25-6)
• EPA Substance Registry System: 2-METHYL-2-PROPAN(OL-D)(3972-25-6)

Safety Data

• Hazard Codes: F,Xn
• Statements: 11-20-36/37
• Safety Statements: 9-16-46
• RIDADR: UN 1120 3/PG 2
• WGK Germany: 3
• Hazardous Substances Data: 3972-25-6(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless liquid

Uses

Different sources of media describe the Uses of 3972-25-6 differently. You can refer to the following data:
1. Tert-butyl Alcohol-OD is used as an organic solvent. Also it is used in the synthesis of proteosome inhibitors that are quite potent.
2. Labelled Tert-butyl Alcohol is used as an organic solvent. Also it is used in the synthesis of proteosome inhibitors that are quite potent.

InChI:InChI=1/C4H10O/c1-4(2,3)5/h5H,1-3H3/i5D

Upstream product

• 75-91-2 tert.-butylhydroperoxide 
• 865-47-4 potassium tert-butylate 
• 1213265-97-4 tetrachloro(N,N'-bis(2,6-diisopropylphenylimino)acenaphthylene)titanium(IV) 
• 1608484-72-5 (R)-N-((S)-(2-(methoxymethoxy)phenyl)(phenyl)methyl)-2-methylpropane-2-sulfinamide 
• 1634-04-4 tert-butyl methyl ether 
• 865-48-5 sodium t-butanolate 
• 540-88-5 acetic acid tert-butyl ester 
• 811-98-3 d⁽⁴⁾-methanol 
• 52258-96-5 3-methyl-3-tert-butylperoxy-1-butyne 
• 75-65-0 tert-butyl alcohol 
• 78957-19-4 dimethylsilyl tert-butylperoxide 
• 14976-54-6 di-tert-butoxydiazene 
• 690-23-3 tert-butyl hydroperoxide-d1 
• 3027-55-2 butoxydipentylborane 

Downstream Products

• 1230074-64-2 cis-3,4-benzo-1,2-diisopropyl-1,2-dimethyl-1,2-disilacyclobut-3-ene 
• 6381-06-2 diphenylstannane 
• 113420-11-4 1-deuteriomethyl-2-(trimethylstannyl)benzene 
• 4314-94-7 benzyl(trimethyl)tin 
• 13537-03-6 PD₃ 
• 13587-50-3 H₂⁽²⁾HP 
• 13780-29-5 H⁽²⁾H₂P 
• 7803-51-2 phosphan 
• 157274-45-8 (CH₃)2Ge(CH₂D)OC(CH₃)3 
• 1449-63-4 trimethylgermane 

Relevant articles and documents

Copper-catalyzed synthesis of CN-containing chroman-4-ones via intramolecular radical cascade acyl-cyanation reaction

A copper-catalyzed intramolecular radical cascade acyl-cyanation to synthesize cyano-containing chroman-4-ones has been developed. A series of CN-substituted chroman-4-one derivatives can be prepared with moderate to good yields using green cyano source under mild conditions. Control experiments indicated this reaction involved an intramolecular acyl radical addition/cyanation process. Moreover, this protocol features step- and atom-economy, and the introduction of cyano group into the chroman-4-one is of great interest and importance.

Photolysis of solutions of 3-terf-butylperoxy-3-methyl-1-butyne

Photolysis of solutions of 3-tert-butyl-3-methyl-1-butyne in CD3OD and C6D12 was studied by means of 1H NMR spectroscopy, chemical nuclear polarization of the reaction products in the range 213-333 K, and kinetic measurements. It is shown that 3-tert-butyl-3-methyl-1-butyne decomposes primarily from a singlet electronic state. A scheme is proposed of the most probable reactions involving the radicals formed and solvent molecules. It is found that secondary processes play an important role in the initiation of the chemical nuclear polarization and the photolysis mechanism.

Phosphonium Phenolate Zwitterion vs Phosphonium Ylide: Synthesis, Characterization and Reactivity Study of a Trimethylphosphonium Phenolate Zwitterion

4-Methoxy-3-(trimethylphosphonio)phenolate was obtained from a regioselective addition of PMe3 to p-quinone monoacetal. This compound undergoes hydrogen isotope exchange with D2O or CD3CN, and is capable of catalyzing H/D exchange of CD3CN with substrates bearing weakly acidic hydrogens. It exhibits similar reactivity to phosphorus ylides for olefinations of aldehydes. A possible tautomerization between the phosphonium phenolate zwitterion and phosphonium ylide is proposed for the first time to rationalize the unique reactivity.