39911-73-4

Basic information

• Product Name: 1-(3,5-dimethoxyphenyl)butan-1-one
• Synonyms: 1-(3,5-dimethoxyphenyl)butan-1-one
• CAS NO: 39911-73-4
• Molecular Weight: 208.257
• Mol File: 39911-73-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(3,5-dimethoxyphenyl)butan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3,5-dimethoxyphenyl)butan-1-one(39911-73-4)
• EPA Substance Registry System: 1-(3,5-dimethoxyphenyl)butan-1-one(39911-73-4)

Safety Data

• Hazardous Substances Data: 39911-73-4(Hazardous Substances Data)

Upstream product

• 17213-58-0 3,5-dimethoxybenzamide 
• 927-77-5 n-propylmagnesium bromide 
• 109480-78-6 N-methoxy-N-methylbutanamide 
• 322640-05-1 3,5-dimethoxyphenyl magnesium bromide 
• 7311-34-4 3,5-dimethoxybenzaldehdye 
• 708253-29-6 1-(3,5-dimethoxyphenyl)butan-1-ol 

Downstream Products

• 39911-75-6 (Z)-2-Cyano-3-(3,5-dimethoxy-phenyl)-hex-2-enoic acid ethyl ester 
• 39911-76-7 2,3-Dicyano-3-(3,5-dimethoxy-phenyl)-hexanoic acid ethyl ester 
• 39911-77-8 Capronsaeure 

Relevant articles and documents

Iridium-Catalyzed Asymmetric Hydrogenation of α-Fluoro Ketones via a Dynamic Kinetic Resolution Strategy

The discrimination of a fluorine atom from a hydrogen atom has been challenging in asymmetric catalysis. We herein report iridium-catalyzed hydrogenation of α-fluoro ketones using a strategy of dynamic kinetic resolution. Both enantiomeric and diastereomeric selectivities were satisfactory in the preparation of β-fluoro alcohols. The DFT calculation revealed a C-F···Na charge-dipole interaction in the transition state of hydride transfer. This noncovalent interaction would be responsible for the diastereomeric control.