39992-52-4Relevant academic research and scientific papers
On the oxidation of 3-ethylpentane under GifIV and Gif-orsay conditions
Barton, Derek H. R.,Doller, Dario,Ozbalik, Nubar,Balavoine, Gilbert,Gref, Aurore,Boivin, Jean
, p. 353 - 356 (1990)
The oxidation of 3-ethylpentane under GifIV (and GoAggII) conditions affords, as major product, 3-acetylpentane and not diethylketone as previously reported. The discrepancy is explained by radical chain autoxidation in presence of a weak tertiary C - H bond.
FUNCTIONALISATION OF SATURATED HYDROCARBONS. Part X. A COMPARATIVE STUDY OF CHEMICAL AND ELECTROCHEMICAL PROCESSES (GIF AND GIF-ORSAY SYSTEMS) IN PYRIDINE, IN ACETONE AND IN PYRIDINE-CO-SOLVENT MIXTURES
Belavoine, Gilbert,Barton, Derek H. R.,Boivin, Jean,Gref, Aurore,Coupanec, Pascale Le,et al.
, p. 1091 - 1106 (2007/10/02)
Six saturated hydrocarbons (cyclohexane, 3-ethylpentane, methylcyclopentane, cis- and trans-decalin and adamantane) were oxidised by the Gif system (iron catalyst, oxygen, zinc, carboxylic acid) and its electrochemical equivalent (Gif-Orsay system).Results obtained using various solvents (pyridine, acetone, pyridine-acetone mixtures) were similar for both systems.Total or partial replacement of pyridine with acetone affects the selectivity for secondary positions and lowers the ketone/secondary alcohol ratio.The formation of the same ratio of cis- and trans-decal-9-ol from both cis- and trans-decalin clearly demonstrates that tertiary alcohols result from a mechanism essentially radical in nature.
Stereochemistry of the Platinum Catalyzed Hydroformylation of Olefins
Haelg, Paul,Consiglio, Giambattista,Pino, Piero
, p. 1865 - 1869 (2007/10/02)
The deuterioformylation of (Z)- or (E)-2-butene catalyzed by Pt(SnCl3)Cl gives predominantly erythro- or threo-1,3-2-2-methylbutanal respectively.Hence, hydroformylation by this catalytic system must take place with cis-stereochemistry.
