Tetrahedron Letters p. 353 - 356 (1990)
Update date:2022-08-03
Topics:
Barton, Derek H. R.
Doller, Dario
Ozbalik, Nubar
Balavoine, Gilbert
Gref, Aurore
Boivin, Jean
The oxidation of 3-ethylpentane under GifIV (and GoAggII) conditions affords, as major product, 3-acetylpentane and not diethylketone as previously reported. The discrepancy is explained by radical chain autoxidation in presence of a weak tertiary C - H bond.
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