On the oxidation of 3-ethylpentane under GifIV and Gif-orsay conditions

DOI: 10.1016/S0040-4039(00)94553-2

Source and publish data:

Tetrahedron Letters p. 353 - 356 (1990)

Update date:2022-08-03

Topics:

Authors:

Barton, Derek H. R.

Doller, Dario

Ozbalik, Nubar

Balavoine, Gilbert

Gref, Aurore

Boivin, Jean

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Article abstract of DOI:10.1016/S0040-4039(00)94553-2

The oxidation of 3-ethylpentane under Gif^IV (and GoAgg^II) conditions affords, as major product, 3-acetylpentane and not diethylketone as previously reported. The discrepancy is explained by radical chain autoxidation in presence of a weak tertiary C - H bond.

Full text of DOI:10.1016/S0040-4039(00)94553-2

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