40010-55-7

Basic information

• Product Name: α-D-[1-¹³C]glucopyranose
• Synonyms: α-D-[1-¹³C]glucopyranose
• CAS NO: 40010-55-7
• Molecular Weight: 181.147
• Mol File: 40010-55-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: α-D-[1-¹³C]glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: α-D-[1-¹³C]glucopyranose(40010-55-7)
• EPA Substance Registry System: α-D-[1-¹³C]glucopyranose(40010-55-7)

Safety Data

• Hazardous Substances Data: 40010-55-7(Hazardous Substances Data)

Upstream product

• 40010-55-7 <1-13C>-α-D-talopyranose 
• 40010-55-7 ¹³C-C₁-glucopyranose 
• 40010-55-7 α- and β-D-<1-13C>mannose 

Downstream Products

• 117013-19-1 <2-13C>-D-fructose 
• 108311-21-3 <1-13C>-D-fructose 
• 105931-74-6 [2-¹³C]-D-mannopyranoside 
• 40010-55-7 α- and β-D-<1-13C>mannose 
• 40762-22-9 [1-13C]D-glucose 
• 40010-56-8 β-D-[1-13C]glucose 
• 287100-63-4 (6-13C)fructose 
• 117013-21-5 β-D-fructopyranose 
• 117013-23-7 [1-¹³C]-α-D-fructofuranose 
• 117013-22-6 [1-¹³C₁]-β-D-fructofuranose 
• 70491-70-2 (6-13C)glucose 
• 115973-81-4 (6-13C)mannose 
• 40010-55-7 ¹³C-C₁-glucopyranose 
• 132202-29-0 <1-13C>Mannitol 

Relevant articles and documents

C-1,C-2 Stereospecific Rearrangements of Aldohexoses by Calcium Ion in Basic Solution

In aqueous or methanolic solution containing Ca(2+) and hydroxide ion, aldoses are rapidly epimerized at C-2.This reaction involves C-1,C-2 stereospecific rearrangement. -D-Mannose is formed from -D-glucose by this reaction.

HYDROXIDE-CATALYZED ISOMERIZATION OF D-(1-13C)MANNOSE: EVIDENCE FOR THE INVOLVEMENT OF 3,4-ENEDIOLS

The KOH-catalyzed isomerization of D-(1-13C)mannose under anaerobic conditions was studied by 13C-n.m.r. spectroscopy.D-(1-13C)Glucose and D-(1-13C)fructose are generated during the reaction, as expected.In addition, however, (6-13C)glucose, (6-13C)mannose, and (6-13C)fructose are produced in small proportions, possibly via symmetrical 3,4-enediol intermediates.The involvement of the latter structures in 13C-label shifting is inferred from the observation of (1-13C)sorbose and (6-13C)sorbose in the reaction mixture.