400744-13-0Relevant academic research and scientific papers
Palladium(II)-catalyzed mono-and bis-alkenylation of N-acetyl-2-aminobiaryls through regioselective C-H bond activation
Annamalai, Pratheepkumar,Hsu, Kou-Chi,Raju, Selvam,Hsiao, Huan-Chang,Chou, Chih-Wei,Lin, Gu-Ying,Hsieh, Cheng-Ming,Chen, Pei-Ling,Liu, Yi-Hung,Chuang, Shih-Ching
, p. 3840 - 3856 (2018/04/14)
We developed palladium-catalyzed oxidative coupling of olefins with N-acyl 2-aminobiaryls through a sequence of ortho C-H bond activation/alkene insertion/reductive elimination. Furthermore, we controlled the selectivity of mono-and bis-alkenylation products with the solvent effect. The developed protocol was promising for a broad substrate scope ranging from activated olefins with a wide variety of functional groups to unactivated olefins.
Palladium nanomaterials in catalytic intramolecular C-H amination reactions
Chng, Leng Leng,Yang, Jun,Wei, Yifeng,Ying, Jackie Y.
supporting information, p. 9049 - 9052 (2014/08/05)
Supported palladium nanomaterials catalyzed an intramolecular C-H amination reaction to produce carbazoles in moderate to excellent isolated yields, up to 92%. This journal is the Partner Organisations 2014.
