40112-59-2

Upstream product

• 7476-11-1 1,1,3,3-tetraphenylpropane-2-one 
• 64-19-7 acetic acid 
• 96739-41-2 1,3-dihydroperoxy-1,1,3,3-tetraphenyl-2-propanone 
• 56-23-5 tetrachloromethane 
• 7476-10-0 1-hydroxy-1,1,3,3-tetraphenyl-acetone 
• 7726-95-6 bromine 
• 96739-42-3 1,3-dihydroxy-1,1,3,3-tetraphenyl-2-propanone 

Downstream Products

• 3677-76-7 2-methyl-1,1-diphenyl-propan-2-ol 
• 5670-79-1 isopropyl diphenylmethyl ether 
• 101-81-5 Diphenylmethane 
• 36317-60-9 4,4-diphenyl-2-butanol 
• 5670-78-0 ethyl diphenylmethyl ether 
• 71925-65-0 α-Benzhydryl-aethyl-aethylaether 
• 71925-66-1 ethyl-(3,3-diphenyl-propyl)-ether 

Relevant academic research and scientific papers

ELECTRON-TRANSFER PHOTOOXYGENATION OF TETRAPHENYLALLENE FORMATION OF 1,3-DIHYDROPEROXY-1,1,3,3-TETRAPHENYL-2-PROPANONE AND ITS DECOMPOSITION UNDER CHEMILUMINESCENCE

DCA-sensitized electron-transfer photooxygenation of tetraphenylallene (1) in acetonitrile yields benzophenone (3) and polymeric material.In acetone, the yield of 3 is better than twice the amount obtained in acetonitrile and very little of polymeric material is observed.If the acetone solution is worked up immediately after the oxygen consumption ceased, 1,3-dihydroperoxy-1,1,3,3-tetraphenyl-2-propanone (8) is isolated.Its formation is proposed to occur via the peroxyallyl zwitterion 4 and the tetraphenylcyclopropanone (7) (Scheme 1). 8 decomposes slowly into 3, and CO+CO2 (3:1) in neutral solution; in the presence of a base, decomposition is fast, resulting in the formation of two molecules of 3, one molecule of water, and one molecule of CO2.Decomposition of 8 in the presence of various fluorescers and a base yields a bright fluorescence of the additives.