401513-48-2

Upstream product

• 107-05-1 3-chloroprop-1-ene 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 1083213-14-2 (Z)-3-(dimethylphenylsilyl)-2-propen-1-yl methyl carbonate 
• 73183-34-3 bis(pinacol)diborane 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 153724-93-7 2-[(E)-3-chloroprop-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 401513-67-5 2-((E)-4-Benzyloxy-4-phenyl-but-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 
• 401513-63-1 2-((E)-4-Methoxy-4-phenyl-but-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 

Relevant academic research and scientific papers

Additions of functionalized α-substituted allylboronates to aldehydes under the novel Lewis and Br?nsted acid catalyzed manifolds

The stereo- and chemoselectivity in the additions of four model α-substituted allylboronates to benzaldehyde was examined under the standard thermal (uncatalyzed) conditions and the novel Lewis and Br?nsted acid-catalyzed conditions. With either of Sc(OTf

Kinetic Resolution of α-Silyl-Substituted Allylboronate Esters via Chemo- and Stereoselective Allylboration of Aldehydes

We describe the kinetic resolution of α-silyl-substituted allylboronate esters via chiral phosphoric acid-catalyzed chemo-, diastereo- and enantioselective allylboration of aldehydes. This process provides two synthetically versatile enantioenriched compo

Synthesis of optically active boron-silicon bifunctional cyclopropane derivatives through enantioselective copper(I)-catalyzed reaction of allylic carbonates with a diboron derivative

(Chemical Equation Presented) Two for the show: A copper(I)-catalyzed reaction forms boron-silicon bifunctional cyclopropane derivatives from γ-silylated allylic carbonates and a diboron species (see scheme). The reaction is highly enantioselective when a chiral bisphosphine ligand is used. The stereoelectronic effect of the silyl group induces unusual regioselectivity of the boryl-copper(I) addition across the C-C double bond.

MANUFACTURING METHOD OF ORGANOBORON COMPOUND

A manufacturing method for one of, or a mixture of, an optically active allylboron compound and racemic or optically active boryl cyclopropane, including a coupling reaction, in the presence of a catalyst, between allyl compound and diboron compound. It i

1-Silyl-1-boryl-2-alkenes: Reagents for stereodivergent allylation leading to 4-oxy-(E)-1-alkenylboronates and 4-oxy-(Z)-1-alkenylsilanes

Silylboryl reagents for organic synthesis: 1-silyl-1-boryl-2-alkenes (2) were prepared efficiently by gem-silylborylation of α-chloroallyllithium compounds from (dimethylphenylsilyl) (pinacolato)borane (1; see scheme, LDA = lithium diisopropylamide) and w