401513-67-5Relevant academic research and scientific papers
1-Silyl-1-boryl-2-alkenes: Reagents for stereodivergent allylation leading to 4-oxy-(E)-1-alkenylboronates and 4-oxy-(Z)-1-alkenylsilanes
Shimizu, Masaki,Kitagawa, Hirotaka,Kurahashi, Takuya,Hiyama, Tamejiro
, p. 4283 - 4286 (2007/10/03)
Silylboryl reagents for organic synthesis: 1-silyl-1-boryl-2-alkenes (2) were prepared efficiently by gem-silylborylation of α-chloroallyllithium compounds from (dimethylphenylsilyl) (pinacolato)borane (1; see scheme, LDA = lithium diisopropylamide) and w
