401845-44-1Relevant academic research and scientific papers
Syntheses and crystal structures of ferrocenyl derivatives of biphenyl
Lemenovskii,Makarov,Dyadchenko,Bruce,Bruce,Larkin,Averkiev,Starikova,Antipin
, p. 607 - 615 (2007/10/03)
Arylation of ferrocene with substituted biphenyldiazonium tetrafluoroborates afforded 4-bromo-, 4-nitro-, and 4-cyano-4′- ferrocenylbiphenyls. 4-Nitro- and 4-cyano-4′-ferrocenylbiphenyls were studied by X-ray diffraction analysis. In the crystals of 4-nitro-4′- ferrocenylbiphenyl, the molecules are linked via stacking π-π interactions.
Bis(ferrocenyl)mercury as a source of ferrocenyl moiety in Pd-catalyzed reactions of carbon-carbon bond formation
Beletskaya, Irina P.,Tsvetkov, Alexei V.,Latyshev, Gennadij V.,Tafeenko, Victor A.,Lukashev, Nikolai V.
, p. 653 - 663 (2007/10/03)
The application of bis(ferrocenyl)mercury as a source of ferrocenyl group in Pd-catalyzed reactions with aryl halides, acid chlorides and electrophilic alkynes has been demonstrated. The formation of dimethyl-(Z)-2,3-di(ferrocenyl)-2-butenedioate in Pd-catalyzed addition of bis(ferrocenyl)mercury to dimethylacetylenedicarboxylate has been confirmed by X-ray analysis.
