401895-07-6

Upstream product

• 74-85-1 ethene 
• 75749-89-2 1-Methoxy-4-(1-methyl-cyclobut-2-enyl)-benzene 
• 401895-09-8 C₂₆H₃₂O₂ 
• 1712-69-2 1-isopropenyl-4-methoxybenzene 
• 1311260-06-6 tert-butyl ((E)-3-(4-methoxyphenyl)-but-2-en-1-yl) carbonate 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1311260-05-5 tert-butyl (2-(4-methoxyphenyl)but-3-en-2-yl) carbonate 
• 31254-20-3 3-hydroxy-3-(4-methoxyphenyl)-but-1-ene 
• 401895-11-2 C₁₉H₂₂N₂O₃S 
• 401895-13-4 toluene-4-sulfonic acid 3-(4-methoxy-phenyl)-3-methyl-cyclobutyl ester 
• 401895-12-3 3-(4-methoxy-phenyl)-3-methyl-cyclobutanol 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Downstream Products

• 223691-88-1 1-(1,5-dimethyl-1-vinyl-hex-4-enyl)-4-methoxy-benzene 
• 223691-84-7 4-(4-methoxyphenyl)-4-methyl-hex-5-en-1-al 
• 401895-10-1 4-(4-methoxy-phenyl)-4-methyl-hex-5-en-1-ol 

Relevant academic research and scientific papers

Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling

The Pd-catalyzed cross-coupling of racemic tertiary allylic carbonates and allylboronates is described. This reaction generates all-carbon quaternary centers in a highly regioselective and enantioselective fashion. The outcome of these reactions is consistent with a process that proceeds by way of 3,3′-reductive elimination of bis(η1-allyl)palladium intermediates. Strategies for distinguishing the product alkenes and application to the synthesis of (+)-α-cuparenone are also described.

Employment of a cyclobutene ring-opening metathesis reaction towards a concise synthesis of (±)-sporochnol A

A concise formal synthesis of (±)-sporochnol A 1, a naturally occurring feeding deterrent towards herbivorous fish, is described. The target compound was prepared by the employment of a Ru-catalysed cyclobutene ring-opening metathesis reaction with gaseou