40195-49-1

Basic information

• Product Name: 2,4-diphenyl-3-oxobutyric acid methyl ester
• Synonyms: 2,4-diphenyl-3-oxobutyric acid methyl ester
• CAS NO: 40195-49-1
• Molecular Weight: 268.312
• Mol File: 40195-49-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,4-diphenyl-3-oxobutyric acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-diphenyl-3-oxobutyric acid methyl ester(40195-49-1)
• EPA Substance Registry System: 2,4-diphenyl-3-oxobutyric acid methyl ester(40195-49-1)

Safety Data

• Hazardous Substances Data: 40195-49-1(Hazardous Substances Data)

Upstream product

• 616-38-6 carbonic acid dimethyl ester 
• 102-04-5 1,3-Diphenylpropanone 
• 67-56-1 methanol 
• 25369-03-3 2,4-diphenyl-3-oxobutanenitrile 
• 101-41-7 benzeneacetic acid methyl ester 
• 40195-40-2 (Z)-2,4-Diphenyl-3-trimethylsilanyloxy-but-3-enoic acid methyl ester 
• 1068-55-9 isopropylmagnesium chloride 
• 40195-27-5 (1-methoxy-2-phenylvinyloxy)trimethylsilane 
• 920-39-8 isopropylmagnesium bromide 

Downstream Products

• 13148-15-7 2-phenylnaphthalene-1,3-diol 

Relevant articles and documents

Use ofcerium(III) chloride in the reactions of carbonyl compounds with organolithiums or grignard reagents for the suppression of abnormal reactions:1-butyl-1,2,3,4-tetrahydro-1-naphthol

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Reactions of Carbonyl Compounds with Grignard Reagents in the Presence of Cerium Chloride

The addition of Grignard reagents to ketones is significantly enhanced by cerium chloride with remarkable supression of side reactions, particularly enolization.Some esters, which are prone to side reactions, also react readily with Grignard reagents in the presence of cerium chloride to give normal reaction products in reasonable to high yields.