40203-52-9

Basic information

• Product Name: 2-Propenoic acid, 2-methoxy-3-phenyl-, methyl ester, (2Z)-
• Synonyms: 2-Propenoic acid,2-methoxy-3-phenyl-,methyl ester,(2Z);2-Propenoic acid,2-methoxy-3-phenyl-,methyl ester
• CAS NO: 40203-52-9
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol File: 40203-52-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-methoxy-3-phenyl-, methyl ester, (2Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-methoxy-3-phenyl-, methyl ester, (2Z)-(40203-52-9)
• EPA Substance Registry System: 2-Propenoic acid, 2-methoxy-3-phenyl-, methyl ester, (2Z)-(40203-52-9)

Safety Data

• Hazardous Substances Data: 40203-52-9(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 7001-18-5 methyl 2-methoxyacrylate 
• 16141-78-9 methyl 2-dimethoxyphosphoryl-2-methoxyacetate 
• 100-52-7 benzaldehyde 
• 36391-85-2 methyl 3-hydroxy-2-methoxy-3-phenylpropionate 
• 200404-50-8 [Bis-(2,2,2-trifluoro-ethoxy)-phosphoryl]-methoxy-acetic acid methyl ester 
• 200404-47-3 (Diphenyl-phosphinoyl)-methoxy-acetic acid methyl ester 
• 16141-79-0 diethyl (methoxy(methoxycarbonyl)methyl)phosphonate 
• 6362-58-9 methyl phenylpyruvate 
• 77-78-1 dimethyl sulfate 
• 6290-49-9 methyl methoxyacetate 

Downstream Products

• 156-06-9 2-oxo-3-(phenyl)propionic acid 
• 154229-82-0 ((Z)-1-Diazo-3-methoxy-2-oxo-4-phenyl-but-3-enyl)-phosphonic acid dimethyl ester 
• 154230-06-5 ((Z)-3-Methoxy-2-oxo-4-phenyl-but-3-enyl)-phosphonic acid dimethyl ester 
• 90843-50-8 (2Z)-2-methoxy-3-phenylacrylic acid 

Relevant articles and documents

Stereoselective alkenylation of aldehydes with phosphorus carbanions: Preparation of E- and Z-2-alkoxy- and 2-aryloxy-2-alkenoates

Eighteen phosphorus-based alkenylation reagents 1a-6c were synthesized and condensed with n-butyraldehyde 7a and benzaldehyde 7f. They were condensed with the aldehydes 7b-e,g-n to produce 2-methoxy-2-alkenoates 8a-n and 2-phenoxy-2-alkenoates 9a-n. A dis

Stereoselective addition of 2-aminothiophenol to α-alkoxycinnamic acid derivatives - Alternative synthesis of (±)-diltiazem

A stereocontrolled synthesis of (±)-diltiazem by applying nucleophilic addition of 2-aminothiophenol to α-alkoxycinnamic acid derivatives is described.

The Allopolarization Principle and its Applications, IV. Substituent Effects in the Methylation of Enolate Anions

The ratio of O- and C-methylated products in the reaction of the sodium salts of acetophenones 1, propiophenones 3, phenylacetones 5, β-dicarbonyl compounds 12, α-cyanocarbonyl compounds 13, acetaldehyde, propionaldehyde, and diethylketone with dimethyl sulfate, methyl iodide, and trimethyl phosphate in HMPTA has been determined with regard to the effect of substituents.In some cases the influence of solvents, concentration and temperature has also been studied.