402559-30-2

Upstream product

• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 4392-24-9 Cinnamyl bromide 

Downstream Products

• 402559-34-6 (3aR,5S,6S,6aR)-2,2-Dimethyl-6-((E)-3-phenyl-allyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde 
• 402559-32-4 (2'E)-3-O-(3'-phenyl-2'-propenyl)-1,2-O-isopropylidene-α-D-glucofuranose 

Relevant academic research and scientific papers

Synthesis, high-resolution NMR spectroscopic analysis, and single-crystal X-ray diffraction of isoxazoline tetracycles

Three isoxazoline tetracycles were obtained enantiomerically pure by intramolecular 1,3-dipolar cycloaddition. The characterization of the new compounds was performed by high-resolution 1H and 13C NMR spectroscopy. The relative configuration of the new chiral centers was determined by NOESY experiments and confirmed by single-crystal X-ray structural analysis.

'Off-template site' intramolecular nitrone cycloaddition (INC) reactions on sugar-derived allylic ethers - A study on the substituent effect and synthesis of furano-pyrans

Sugar-derived allylic ethers having one or two substituents on the terminal olefinic carbon centre were subjected to intramolecular nitrone cycloaddition (INC) reactions resulting in bicyclo[4.3.0] systems. The exclusiveness of product formation may be attributed to the effect of substituents.