402849-67-6

Basic information

• Product Name: ethyl 2-deoxy-4,5,6,8-tetra-O-benzyl-α-D-galacto-3,7-pyranoso-3-octulosonate
• Synonyms: ethyl 2-deoxy-4,5,6,8-tetra-O-benzyl-α-D-galacto-3,7-pyranoso-3-octulosonate
• CAS NO: 402849-67-6
• Molecular Weight: 626.747
• Mol File: 402849-67-6.mol

Chemical Properties

• CAS DataBase Reference: ethyl 2-deoxy-4,5,6,8-tetra-O-benzyl-α-D-galacto-3,7-pyranoso-3-octulosonate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-deoxy-4,5,6,8-tetra-O-benzyl-α-D-galacto-3,7-pyranoso-3-octulosonate(402849-67-6)
• EPA Substance Registry System: ethyl 2-deoxy-4,5,6,8-tetra-O-benzyl-α-D-galacto-3,7-pyranoso-3-octulosonate(402849-67-6)

Safety Data

• Hazardous Substances Data: 402849-67-6(Hazardous Substances Data)

Upstream product

• 141-78-6 ethyl acetate 
• 82598-84-3 2,3,4,6-tetra-O-benzyl-D-galactonolactone 
• 105-36-2 ethyl bromoacetate 

Downstream Products

• 214771-14-9 (1(1')-Z)-2,3,4,6-tetra-O-benzyl-1-deoxy-1-(ethoxycarbonyl)methylidene-D-galactopyranose 

Relevant articles and documents

Two ethyl 2-deoxy-α-D-hexo-3,7-pyranoso-3-octulosonate derivatives

Conformations of two ethyl 2-dexoy-α-D-hexo-3,7-pyranoso-3-octulosonate derivatives were studied. In each structure the anomeric hydroxy group formed an intramolecular hydrogen bond with the carbonyl O atom of the ethoxy-carbonylmethyl substituent. The co

Stereochemistry in the synthesis and reaction of exo-glycals.

Two general methods are explored for the stereoselective synthesis of exo-glycals. One method utilizes a nucleophilic addition of fully protected sugar lactones of gluco-, galacto-, and manno-types, followed by the subsequent dehydration, to give the desired exo-glycals with (Z)-configuration. The other method proceeds with selenylation of C-glycosides in a stereoselective manner. The subsequent selenoxide elimination also provides (Z)-exo-glycals. The prepared exo-glycal conjugated esters of either gluco- or manno-type react with allyl alcohol to give exclusively alpha-anomers.