403500-73-2

Upstream product

• 403500-67-4 C₆H₁₀O₄(C₃H₄)Si(CH₃)2C₄H₈OHNCOSO₂C₆H₄CH₂ 
• 403500-66-3 N-[(5S,8R,9R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-9-hydroxy-2,2-dimethyl-1,3,6-trioxa-spiro[4.5]dec-8-yl]-4-methyl-benzenesulfonamide 
• 403500-68-5 C₆H₁₀O₄(C₃H₄)Si(CH₃)2C₄H₈OHNCO 
• 335233-12-0 tert-Butyl-((5S,10S)-2,2-dimethyl-1,3,6-trioxa-spiro[4.5]dec-8-en-10-yloxy)-dimethyl-silane 
• 76573-34-7 (-)-3-deoxy-1,2:4,5-di-O-isopropylidene-β-D-fructofuranos-3-yl benzoate 
• 99648-51-8 (2S,3S)-3,6-dihydro-3-hydroxy-2',2'-dimethyl-2H-pyran-2-spiro-4'-(1',3'-dioxolane) 
• 99648-50-7 3-O-benzoyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose 
• 99648-49-4 3-O-benzoyl-1,2-O-isopropylidene-β-D-fructopyranose 
• 7660-25-5 D-fructose 
• 25018-67-1 1,2;4,5-di-O-isopropylidene-β-D-(-)-fructopyranose 
• 403500-72-1 C₆H₁₀O₄(C₃H₄)Si(CH₃)2C₄H₈OHNCOCHC₆H₅ 

Relevant academic research and scientific papers

Electronic probing of ketone catalysts for asymmetric epoxidation. Search for more robust catalysts

Equation presented Ketones with a fused oxazolidinone were synthesized and investigated to determine the electronic effect of the substituents at α-positions of ketone catalysts on the Baeyer-Villiger oxidation and catalytic properties for asymmetric epoxidation. These new ketones give high yields and ee's with only 1 5 mol % catalyst. The current studies further show that the electronic effect is very important for the kitone-catalyzed epoxidation.