99648-50-7

Upstream product

• 76573-34-7 (-)-3-deoxy-1,2:4,5-di-O-isopropylidene-β-D-fructofuranos-3-yl benzoate 
• 98-88-4 benzoyl chloride 
• 7660-25-5 D-fructose 
• 25018-67-1 1,2;4,5-di-O-isopropylidene-β-D-(-)-fructopyranose 
• 99648-48-3 3-O-benzoyl-1,2-O-isopropylidene-4,5-di-O-mesyl-β-D-fructopyranose 
• 99648-49-4 3-O-benzoyl-1,2-O-isopropylidene-β-D-fructopyranose 

Downstream Products

• 403500-67-4 C₆H₁₀O₄(C₃H₄)Si(CH₃)2C₄H₈OHNCOSO₂C₆H₄CH₂ 
• 403500-66-3 N-[(5S,8R,9R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-9-hydroxy-2,2-dimethyl-1,3,6-trioxa-spiro[4.5]dec-8-yl]-4-methyl-benzenesulfonamide 
• 403500-72-1 C₆H₁₀O₄(C₃H₄)Si(CH₃)2C₄H₈OHNCOCHC₆H₅ 
• 403500-73-2 C₆H₁₀O₄(C₃H₄)OHNCOCHC₆H₅ 

Relevant academic research and scientific papers

Controlled Garegg conditions for selective iodination on pyranose templates

Regio- and stereoselective iodinations under controlled Garegg conditions were performed on vicinal diols and contiguous triols located on pyranose templates. β-D-Fructo- orpsicopyranose-based diols were selectively iodinated at C-5 or C-4, respectively,

Electronic probing of ketone catalysts for asymmetric epoxidation. Search for more robust catalysts

Equation presented Ketones with a fused oxazolidinone were synthesized and investigated to determine the electronic effect of the substituents at α-positions of ketone catalysts on the Baeyer-Villiger oxidation and catalytic properties for asymmetric epoxidation. These new ketones give high yields and ee's with only 1 5 mol % catalyst. The current studies further show that the electronic effect is very important for the kitone-catalyzed epoxidation.

Studies on Ketoses, 2. Spirocyclic Dihydropyranes from D-Fructose

Expedient reaction sequences have been developed to concert D-fructose into a diverse collection of spirocyclic dihydropyrandiols with 2S,3S (10,11), 2R,5S (17,18), and 2S,3R configuration (19), and of dihydropyranones 4 - 7 with 2S and 2R chirality.Due t