403519-45-9

Basic information

• Product Name: 2-Buten-1-ol, 3-(2-methoxy-5-methylphenyl)-, (2E)-
• CAS NO: 403519-45-9
• Molecular Formula: C12H16O2
• Molecular Weight: 192.258
• Mol File: 403519-45-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Buten-1-ol, 3-(2-methoxy-5-methylphenyl)-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Buten-1-ol, 3-(2-methoxy-5-methylphenyl)-, (2E)-(403519-45-9)
• EPA Substance Registry System: 2-Buten-1-ol, 3-(2-methoxy-5-methylphenyl)-, (2E)-(403519-45-9)

Safety Data

• Hazardous Substances Data: 403519-45-9(Hazardous Substances Data)

Upstream product

• 433732-64-0 ethyl E-3-(2-methoxy-5-methylphenyl)but-2-enoate 
• 20628-07-3 2-acetyl-4-methylanisole 

Downstream Products

• 433732-69-5 3-(2-methoxy-5-methyl-phenyl)-3-methyl-pent-4-enal 
• 403519-47-1 ethyl 2-allyl-3-(2-methoxy-5-methylphenyl)-3-methylpent-4-enoate 
• 403519-48-2 ethyl 2-methyl-2-(2-methoxy-5-methylphenyl)cyclopent-3-enecarboxylate 
• 433732-72-0 5-(2-methoxy-5-methyl-phenyl)-5-methyl-hepta-1,6-dien-3-ol 
• 433732-75-3 4-(2-methoxy-5-methyl-phenyl)-4-methyl-cyclopent-2-enol 
• 433732-78-6 4-(2-methoxy-5-methyl-phenyl)-4-methyl-cyclopent-2-enone 
• 403519-46-0 ethyl 3-methyl-3-(2-methoxy-5-methylphenyl)pent-4-enoate 

Relevant articles and documents

Construction of vicinal quaternary carbon atoms by Ireland ester Claisen rearrangement: Total synthesis of (±)-herbertenolide, (±)-herberteneacetal, (±)-herbertene-1,14-diol and (±)-herbertene-1,15-diol

Efficient total syntheses of the herbertane sesquiterpene title compounds have been accomplished employing an Ireland ester Claisen rearrangement and ring-closing metathesis reaction sequence based strategy for the construction of two stereogenic vicinal quaternary carbon atoms on a cyclopentane.

A simple, ring-closing metathesis reaction based approach to (±)-1,14-herbertenediol and (±)-11-epi-herbertenolide

A total synthesis of 1,14-herbertenediol via 11-epi-herbertenolide, and a formal total synthesis of tochuinyl acetate and dihydrotochuinyl acetate, employing a ring-closing metathesis reaction based methodology, are described.