433732-64-0

Upstream product

• 20628-07-3 2-acetyl-4-methylanisole 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 105-36-2 ethyl bromoacetate 

Downstream Products

• 14002-89-2 4,6-dimethyl-chromen-2-one 
• 403519-45-9 E-3-(2-methoxy-5-methylphenyl)but-2-en-1-ol 
• 403519-47-1 ethyl 2-allyl-3-(2-methoxy-5-methylphenyl)-3-methylpent-4-enoate 
• 403519-46-0 ethyl 3-methyl-3-(2-methoxy-5-methylphenyl)pent-4-enoate 
• 403519-48-2 ethyl 2-methyl-2-(2-methoxy-5-methylphenyl)cyclopent-3-enecarboxylate 
• 433732-72-0 5-(2-methoxy-5-methyl-phenyl)-5-methyl-hepta-1,6-dien-3-ol 
• 433732-69-5 3-(2-methoxy-5-methyl-phenyl)-3-methyl-pent-4-enal 
• 433732-75-3 4-(2-methoxy-5-methyl-phenyl)-4-methyl-cyclopent-2-enol 
• 433732-78-6 4-(2-methoxy-5-methyl-phenyl)-4-methyl-cyclopent-2-enone 

Relevant academic research and scientific papers

NTETRAHYDROPYRIDOTHIOPHENE DERIVATIVES FOR THE TREATMENT OF CANCER

Compounds of a certain formula (I), in which Ra and Rb have the meanings indicated in the description, are novel effective compounds with anti-proliferative and apoptosis inducing activity.

Construction of vicinal quaternary carbon atoms by Ireland ester Claisen rearrangement: Total synthesis of (±)-herbertenolide, (±)-herberteneacetal, (±)-herbertene-1,14-diol and (±)-herbertene-1,15-diol

Efficient total syntheses of the herbertane sesquiterpene title compounds have been accomplished employing an Ireland ester Claisen rearrangement and ring-closing metathesis reaction sequence based strategy for the construction of two stereogenic vicinal quaternary carbon atoms on a cyclopentane.

A simple, ring-closing metathesis reaction based approach to (±)-1,14-herbertenediol and (±)-11-epi-herbertenolide

A total synthesis of 1,14-herbertenediol via 11-epi-herbertenolide, and a formal total synthesis of tochuinyl acetate and dihydrotochuinyl acetate, employing a ring-closing metathesis reaction based methodology, are described.

A ring closing metathesis-based approach to (±)-herbertene, (±)-α-herbertenol, (±)-β-herbertenol and (±)-herbertenediol

An efficient methodology for the synthesis of the aromatic sesquiterpenes (±)-herbertene, (±)-α-herbertenol, (±)-β-herbertenol (±)-herbertenediol and (±)-α-cuparenone, employing a combination of Claisen rearrangement and ring closing metathesis reactions,