403611-08-5

Basic information

• Product Name: Cyclopropane, 1-(5-hexen-1-ynyl)-2-methyl-, (1R,2R)-rel- (9CI)
• Synonyms: Cyclopropane, 1-(5-hexen-1-ynyl)-2-methyl-, (1R,2R)-rel- (9CI)
• CAS NO: 403611-08-5
• Molecular Formula: C10H14
• Molecular Weight: 134.21816
• Mol File: 403611-08-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopropane, 1-(5-hexen-1-ynyl)-2-methyl-, (1R,2R)-rel- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropane, 1-(5-hexen-1-ynyl)-2-methyl-, (1R,2R)-rel- (9CI)(403611-08-5)
• EPA Substance Registry System: Cyclopropane, 1-(5-hexen-1-ynyl)-2-methyl-, (1R,2R)-rel- (9CI)(403611-08-5)

Safety Data

• Hazardous Substances Data: 403611-08-5(Hazardous Substances Data)

Upstream product

• 5162-44-7 1-bromo-4-butene 
• 52114-14-4 trans-(2-Methylcyclopropyl)acetylene 
• 122519-86-2 1,1-Dichloro-1-(trans-2-methylcyclopropyl)ethane 
• 930-56-3 Methyl trans-2-methylcyclopropyl ketone 
• 3620-18-6 3-acetyl-5-methyldihydrofuran-2(3H)-one 
• 102438-65-3 2-chlorohexan-5-one 

Relevant articles and documents

Thermal pericyclic tandem reactions

Gas phase thermal isomerizations of twelve acetylenic systems, all of which can in principle undergo two successive pericyclic steps, are described. The substrates, the syntheses and spectroscopic properties of which are presented, are formal derivatives of but-2-yne, with different functional groups in the 1- and the 4-positions. The Cope, Claisen, Claisen ester, retro-ene, 1,5-hydrogen shift, and 1,5-homo hydrogen-shift processes were employed as the pericyclic steps from which the tandem processes were composed. The compositions of the pyrolysates obtained were determined over broad temperature ranges, and the mechanisms of the individual steps producing the pyrolysis products are discussed.