40395-23-1Relevant articles and documents
SN2'-Regio- and Diastereoselective Allylation of Organozine Raegents
Arai, Masayuki,Kawasuji, Takashi,Nakamura, Eiichi
, p. 357 - 360 (1993)
Dialkylzinc reagents, R2Zn and R2Zn*LiCl, undergo an SN2'-regio- and diastereoselective allylation reaction with substituted allylic chlorides and phosphates in the presence of a coordinating additive.
Catalyst-controlled reverse selectivity in C-C bond formation: NHC-Cu-catalyzed α-selective allylic alkylation with organolithium reagents
Pizzolato, Stefano F.,Giannerini, Massimo,Bos, Pieter H.,Fa?anás-Mastral, Martín,Feringa, Ben L.
, p. 8142 - 8145 (2015/05/20)
An efficient and highly α-selective copper-catalyzed allylic alkylation of allylic halides with organolithium reagents is presented. The use of N-heterocyclic carbenes as ligands is key to reverse the common γ-selectivity of this transformation and gives rise to the corresponding linear products with high levels of regioselectivity.
Short synthesis of chiral 4-substituted (S)-imidazolinium salts bearing sulfonates and their use in γ-selective reactions of allylic halides with grignard reagents
Latham, Christopher M.,Blake, Alexander J.,Lewis, William,Lawrence, Matthew,Woodward, Simon
supporting information; experimental part, p. 699 - 707 (2012/03/11)
A one-pot reaction of Boc-protected amino alcohols and 2-sulfobenzoic anhydride followed by the addition of a wide variety of primary amines has allowed rapid access to diverse libraries of amidosulfonates 1,2-C 6H4(SO3su
