40414-70-8

Upstream product

• 74-96-4 ethyl bromide 
• 98-86-2 acetophenone 
• 109-94-4 formic acid ethyl ester 
• 98-88-4 benzoyl chloride 
• 109-92-2 ethyl vinyl ether 

Downstream Products

• 6465-14-1 ethyl 2-oxo-6-phenyl-2H-pyran-3-carboxylate 
• 1006-65-1 3-phenylisoxazole 
• 98-86-2 acetophenone 
• 3617-16-1 Benzoylacetaldehyde ω-semicarbazone 
• 4492-01-7 1,3-diphenyl-1H-pyrazole 
• 69413-39-4 3-phenyl-pyrazole-1-carboxylic acid amide 
• 1034638-31-7 3-hydroxy-4-(3-phenylpropyl)biphenyl-2-carboxylic acid methyl ester 
• 1034638-35-1 C₁₁H₁₁BrO₂ 
• 1140530-71-7 methyl 3-(4-chlorophenylsulfanyl)biphenyl-2-carboxylate 
• 1140530-70-6 methyl 3-phenylsulfanylbiphenyl-2-carboxylate 
• 1443678-74-7 (E)-3-ethoxy-1-phenyl-2-(phenylethynyl)prop-2-en-1-one 
• 1443678-83-8 4-iodo-2,5-diphenylfuran-3-carbaldehyde 
• 1443678-87-2 3-benzoyl-4-iodo-5-phenylfuran 
• 1443678-84-9 4-iodo-2-phenyl-5-(4-methoxy)phenylfuran-3-carbaldehyde 

Relevant academic research and scientific papers

Enol ethers and acetals: Acylation with dichloroacetyl, acetyl and benzoyl chloride in ionic liquid medium

Synthesis of 4-alkoxy-1,1-dichloro-3-alken-2-ones [CHCl2C(O) C(R2)C(R1)-OR, where R, R1, R2 = Et, H, H; Me, Me, H; Et, H, Me; Me, -(CH2)2-; Me, -(CH 2)3-; Et, Et, H; Et, Bu, H; Et, i-Pr, H; Et, i-Bu, H; Me, Ph, H; Me, thien-2-yl, H] from acylation of enol ethers and acetals with dichloroacetyl chloride, in ionic liquid ([BMIM][BF4] or [BMIM][PF6]) is reported. The synthesis of alkenones [R 3-C(O)C(R2)C(R1)-OR], where R/R 1/R2/R3 = Et/H/H/Ph, t-Bu/H/H/Ph, Me/-(CH 2)4/Ph, Me/-(CH2)4/Me] from the reaction of enol ethers with benzoyl chloride or acetyl chloride, in ionic liquid [BMIM][BF4], is also reported. Last products are described for the first time.

Efficient palladium-catalyzed Suzuki cross-coupling reaction with β-ketoamine ligands

A series of β-ketoamine ligands with different steric and electronic substituents on the backbone and with aniline moieties have been synthesized and characterized. In the presence of PdCl2, catalytic studies indicated that they are effective l

Cyclo-ruthenated and -platinated complexes bearing phosphonate substituents

Two new, potentially cyclometalating terdentate ligands bearing phosphonate substituents, Et2O3P-N^C(H)^N (5) and Et2O3P-C(H)^N^N (7), have been prepared. The corresponding ruthenium complexes, [1]+ and [2]+, respectively, were obtained by reaction with [RuCl3(tpy)]. Complexes [1]+ and [2]+ display electronic properties characteristic for cyclometalated ruthenium complexes. The platinum complex [3], of N^C(H)^N ligand 5, was also prepared and is highly phosphorescent in solution. In general, the phosphonate group electronically behaves equivalent to a carboxylate moiety.

Synthesis of functionalized salicylates by formal [3+3] cyclocondensation of 1,3-bis(silyloxy)buta-1,3-dienes with 3-alkoxy-2-en-1-ones

The formal [3+3] cyclization of 1,3-bis(silyloxy)buta-1,3-dienes with 1-aryl-3-ethoxyprop-2-en-1-ones, available by Heck reaction of benzoyl chlorides with ethyl vinyl ether, afforded a variety of 6-arylsalicylates. The reaction of the products with conce

Synthesis of functionalized biaryls based on a heck cross-coupling-[3+3] cyclization strategy

6-Arylsalicylates were regioselectively prepared by formal [3+3] cyclization of 1,3-bis(silyloxy)-1,3-butadienes with 1-aryl-3-ethoxyprop-2-en-1- ones which are available by Heck reaction of benzoyl chlorides with ethylvinyl ether. In this context, the first [3+3] cyclizations of brominated substrates are reported. Georg Thieme Verlag Stuttgart.