4043-69-0Relevant academic research and scientific papers
1H-INDAZOLES AS SYNTHETIC AUXILIARIES FOR THE SYNTHESIS OF SECONDARY AROMATIC AMINES
Saladino, Raffaele,Crestini, Claudia,Nicoletti, Rosario
, p. 567 - 574 (2007/10/02)
Methodology of alkylation of aromatic amines using 1H-indazoles as synthetic auxiliares is reported.
Catalytic aminomercuration of olefins in a tandem aminomercuration-deoxymercuration; one-step synthesis of secondary n-arylallylamines from allylalcohols
Barluenga, Jose,Perez-Prieto, Julia,Asensio, Gregorio
, p. 2453 - 2460 (2007/10/02)
Allyl alcohols react with primary aromatic amines and stoichiometric amounts of mercury(II) tetrafluoroborate to give mixtures of mono- and diallyl anilines. However, the use of the tandem aminomercuration-deoxymercuration promoted by catalytic mercury(II) tetrafluoroborate allows to perform regiospecifically the monoallylation reaction with very high yields. A mechanism is proposed to account for the observed results.
