405555-55-7

Basic information

• Product Name: Pt⁽²⁺⁾*C₆H₅^(1-)*NC₅H₄NC₅H₂C₆H₅^(1-)*(CH₃)2SO=(Pt(C₆H₅)(NC₅H₄NC₅H₂C₆H₅)((CH₃)2SO))
• CAS NO: 405555-55-7
• Molecular Weight: 581.597
• Mol File: 405555-55-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt⁽²⁺⁾*C₆H₅^(1-)*NC₅H₄NC₅H₂C₆H₅^(1-)*(CH₃)2SO=(Pt(C₆H₅)(NC₅H₄NC₅H₂C₆H₅)((CH₃)2SO))(CAS DataBase Reference)
• NIST Chemistry Reference: Pt⁽²⁺⁾*C₆H₅^(1-)*NC₅H₄NC₅H₂C₆H₅^(1-)*(CH₃)2SO=(Pt(C₆H₅)(NC₅H₄NC₅H₂C₆H₅)((CH₃)2SO))(405555-55-7)
• EPA Substance Registry System: Pt⁽²⁺⁾*C₆H₅^(1-)*NC₅H₄NC₅H₂C₆H₅^(1-)*(CH₃)2SO=(Pt(C₆H₅)(NC₅H₄NC₅H₂C₆H₅)((CH₃)2SO))(405555-55-7)

Safety Data

• Hazardous Substances Data: 405555-55-7(Hazardous Substances Data)

Upstream product

• 61633-06-5 6-phenyl-2,2'-bipyridine 

Downstream Products

• 405555-57-9 (C₆H₅)((CH₃)2SO)PtNC₅H₃NC₅H₂C₆H₄Pt((CH₃)2SO) 

Relevant articles and documents

Activation of a C-H bond in a pyridine ring. Reaction of 6-substituted 2,2′-bipyridines with the methyl and phenyl platinum(II) derivatives: N′,C(3)- rollover cyclometalation

The reaction of the electron-rich derivatives cis-[Pt(R)2(DMSO)2] (R = Me, Ph) with a series of 6-substituted-2,2′-bipyridines, HL, occurs with loss of methane or benzene, respectively, to yield cyclometalated platinum(II) species [Pt(R)(L)(DMSO)]where L is an anionic ligand N′,C(3) coordinated. The unusual C-H activation entails a consecutive reaction process through a detectable intermediate. The reaction is peculiar of 6-substituted ligands: for comparison no reaction occurs with 6,6′-Me2-2,2′-bipy and an adduct, [Pt(R)2(HL)], is obtained with 5-Me-2,2′-bipy.