61633-06-5

Basic information

• Product Name: 6-Phenyl-2,2'-bipyridine
• Synonyms: 6-Phenyl-2,2'-bipyridine
• CAS NO: 61633-06-5
• Molecular Formula: C₁₆H₁₂N₂
• Molecular Weight: 232.28
• Mol File: 61633-06-5.mol
• Article Data: 14

Chemical Properties

• Melting Point: 83.5-84.5 °C(Solv: ligroine (8032-32-4); ethyl ether (60-29-7))
• Boiling Point: 390.3±27.0 °C(Predicted)
• Appearance: /
• Density: 1.125±0.06 g/cm3(Predicted)
• PKA: 4.06±0.22(Predicted)
• CAS DataBase Reference: 6-Phenyl-2,2'-bipyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Phenyl-2,2'-bipyridine(61633-06-5)
• EPA Substance Registry System: 6-Phenyl-2,2'-bipyridine(61633-06-5)

Safety Data

• Hazardous Substances Data: 61633-06-5(Hazardous Substances Data)

Upstream product

• 366-18-7 [2,2]bipyridinyl 
• 10495-73-5 2-bromo-6-(pyridin-2-yl)pyridine 
• 98-80-6 phenylboronic acid 
• 591-50-4 iodobenzene 
• 109-04-6 2-bromo-pyridine 
• 39774-26-0 2-bromo-6-phenylpyridine 
• 1078-58-6 diphenylzinc 
• 591-51-5 phenyllithium 
• 698-16-8 benzohydroximoyl chloride 
• 134370-20-0 2-(3-Phenyl-4,5-dihydro-isoxazol-5-yl)-1-pyridin-2-yl-ethanol 
• 17285-57-3 1-(2-pyridinyl)but-3-en-1-ol 
• 134370-32-4 5-<2-Oxo-2-(2-pyridyl)ethyl>-3-phenyl-2-isoxazoline 
• 879-72-1 3-(dimethylamino)propiophenone hydrochloride 
• 26482-00-8 1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide 

Downstream Products

• 889663-80-3 bis(6-phenyl-2,2'-bipyridine)copper(I) hexafluorophosphate 
• 151709-49-8 Ru((C₅H₄N)2C₅H₂NC₆H₄CH₃)(C₅H₄NC₅H₃NC₆H₅)Cl⁽¹⁺⁾*PF₆^(1-)={Ru((C₅H₄N)2C₅H₂NC₆H₄CH₃)(C₅H₄NC₅H₃NC₆H₅)Cl}PF₆ 
• 151709-47-6 Ru((C₅H₄N)2C₅H₃N)(C₅H₄NC₅H₃NC₆H₅)Cl⁽¹⁺⁾*PF₆^(1-)={Ru((C₅H₄N)2C₅H₃N)(C₅H₄NC₅H₃NC₆H₅)Cl}PF₆ 
• 151709-51-2 Ru((C₅H₄N)2C₅H₂NC₆H₅)(C₅H₄NC₅H₃NC₆H₅)Cl⁽¹⁺⁾*PF₆^(1-)={Ru((C₅H₄N)2C₅H₂NC₆H₅)(C₅H₄NC₅H₃NC₆H₅)Cl}PF₆ 
• 324576-64-9 [PtCl(methyl)(6-phenyl-2,2'-bipyridine)] 
• 405555-54-6 (CH₃)Pt(NC₅H₄NC₅H₂C₆H₅)((CH₃)2SO) 
• 405555-57-9 (C₆H₅)((CH₃)2SO)PtNC₅H₃NC₅H₂C₆H₄Pt((CH₃)2SO) 
• 151709-47-6 Ru(C₁₅H₁₁N₃)Cl(C₁₆H₁₂N₂)⁽¹⁺⁾*PF₆^(1-) = [Ru(C₁₅H₁₁N₃)Cl(C₁₆H₁₂N₂)][PF₆] 
• 405555-55-7 Pt⁽²⁺⁾*C₆H₅^(1-)*NC₅H₄NC₅H₂C₆H₅^(1-)*(CH₃)2SO=(Pt(C₆H₅)(NC₅H₄NC₅H₂C₆H₅)((CH₃)2SO)) 
• 405555-54-6 [PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))] 

Relevant articles and documents

Cyclometallation Reactions of 6-Phenyl-2,2'-bipyridine, a Potential C,N,N-Donor Analogue of 2,2':6',2''-Terpyridine. Crystal and Molecular Structure of Dichlorobis(6-phenyl-2,2'-bipyridine)ruthenium(II)

Metallated and non-metallated complexes of the ligand 6-phenyl-2,2'-bipyridine (HL) with ruthenium(II), rhodium(III), platinum(II), palladium(II), and gold(III) have been prepared.The crystal and molecular structure of the complex indicates that it contains two N-bonded ligands and a cis arrangement of the chlorides.

The cyclometalated nickel complex [(Phbpy)NiBr] (Phbpy- = 2,2′-bipyridine-6-phen-2-yl) - Synthesis, spectroscopic and electrochemical studies

The new organometallic nickel complex [(Phbpy)NiBr] containing the anionic tridentate N,N,C ligand 6-(phen-2-yl)-2,2′-bipyridine (Phbpy-) was synthesised from PhbpyBr and [Ni(COD)2] in excellent yields and was fully characterised (MS

Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions

Dinuclear pincer-type cyclometalated Pd(ii) complexes with foldable diacetylide ligands show crystallographically determined intramolecular Pd?Pd contacts of 3.203-3.380 ?. In deoxygenated fluid solutions, these Pd(ii) complexes are highly phosphorescent

Iron catalyzed oxidative assembly of N-heteroaryl and aryl metal reagents using oxygen as an oxidant

An equivalent amount of N-heteroaryl and aryl Grignard or lithium reagents, after mediation by an equivalent of titanate, was facilely coupled to furnish N-heteroaryl-aryl compounds under the catalysis of FeCl3/TMEDA at ambient temperature using oxygen as an oxidant. Most of the common N-heteroaryls were all good candidates, and thus provided a general, green and pratical protocol for the flexible construction of various N-heteroaryl-aryl structures. This journal is