40564-61-2

Usage

InChI:InChI=1/C8H14O3/c1-6(2)7(9)4-3-5-8(10)11/h6H,3-5H2,1-2H3,(H,10,11)

Upstream product

• 857480-67-2 2-(2-cyano-ethyl)-4-methyl-3-oxo-valeric acid ethyl ester 
• 92984-42-4 2-isobutyryl-glutaric acid diethyl ester 
• 562-13-0 2,2-dimethyl-1,3-cyclohexanedione 
• 2758-17-0 2-isopropylidenecyclopentan-1-one 
• 1462-07-3 1-isopropylcyclopentene 
• 73267-98-8 1-isopropylcyclopentene-1 ozonide 
• 7152-15-0 ethyl 4-methyl-3-oxo-pentanoate 
• 108-55-4 glutaric anhydride, 
• 920-39-8 isopropylmagnesium bromide 
• 1068-55-9 isopropylmagnesium chloride 
• 120-92-3 cyclopentanone 
• 1462-06-2 1-cyclopentyl-1-methylethanol 

Downstream Products

• 24071-98-5 ethyl 5-oxo-5-isopropylpentanoate 
• 120109-90-2 ethyl 5-(4-chlorobenzylimino)-6-methylheptanoate 
• 120109-89-9 ethyl 5-(4-fluorobenzylimino)-6-methylheptanoate 
• 120109-93-5 ethyl 5-(4-chlorobenzylamino)-6-methylheptanoate 
• 120109-92-4 ethyl 5-(4-fluorobenzylamino)-6-methylheptanoate 
• 120109-91-3 ethyl 5-benzylimino-6-methylheptanoate 
• 120109-94-6 ethyl 5-benzylamino-6-methylheptanoate 
• 120109-82-2 1-(4-chlorobenzyl)-6-isopropyl-2-piperidinone 
• 120109-95-7 1-(4-fluorobenzyl)-6-isopropyl-2-piperidinone 
• 120109-83-3 1-benzyl-6-isopropyl-2-piperidinone 
• 127749-58-0 N-(4-fluorobenzyl)-6-methyl-5-oxo-nonanamide 

Relevant academic research and scientific papers

Synthesis of γ-, δ-, and ε-lactams by asymmetric transfer hydrogenation of N-(tert-butylsulfinyl)iminoesters

Highly enantiomerically enriched γ- and δ-lactams have been prepared by a simple and very efficient procedure that involves the asymmetric transfer hydrogenation of N-(tert-butylsulfinyl)iminoesters followed by desulfinylation of the nitrogen atom and spo

Silver-catalyzed radical phosphonofluorination of unactivated alkenes

We report herein a mild and catalytic phosphonofluorination of unactivated alkenes. With catalysis by AgNO3, the condensation of various unactivated alkenes with diethyl phosphite and Selectfluor reagent in CH 2Cl2/H2O/HOAc at 40 C led to the efficient synthesis of β-fluorinated alkylphosphonates with good stereoselectivity and wide functional group compatibility. A mechanism involving silver-catalyzed oxidative generation of phosphonyl radicals and silver-assisted fluorine atom transfer is proposed.

Tertiary aminourea-catalyzed enantioselective iodolactonization

Binding the anion : A highly enantioselective iodolactonization of 5-hexenoic acids has been achieved using a tertiary aminourea-catalyst (see scheme). The use of catalytic iodine in this process is critical to enhancing both the reactivity and enantioselectivity of the stoichiometric I+ source. The mechanism is proposed to involve binding of an iodonium imidate intermediate by the H-bond donor catalyst.

Synthesis and studies of piperidinone, the major metabolite of a new antidepressant drug S 3344

The synthesis of 1-(4-fluorobenzyl)-6-isopropyl-2-piperidinone 7a, a major metabolite of a new antidepressant S 3344, is described and then substituted with various substituents. The 1H and 13C nmr provide information on their struct