40582-90-9

Basic information

• Product Name: p-chlorophenyl 2-phenylhexyl sulfone
• Synonyms: p-chlorophenyl 2-phenylhexyl sulfone
• CAS NO: 40582-90-9
• Molecular Weight: 336.883
• Mol File: 40582-90-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: p-chlorophenyl 2-phenylhexyl sulfone(CAS DataBase Reference)
• NIST Chemistry Reference: p-chlorophenyl 2-phenylhexyl sulfone(40582-90-9)
• EPA Substance Registry System: p-chlorophenyl 2-phenylhexyl sulfone(40582-90-9)

Safety Data

• Hazardous Substances Data: 40582-90-9(Hazardous Substances Data)

Upstream product

• 24406-16-4 lithium di-n-butylcuprate 
• 100-52-7 benzaldehyde 
• 40137-12-0 diethyl<<(p-chlorophenyl)sulfonyl>methyl>phosphonate 
• 69770-58-7 diethyl<<(p-chlorophenyl)sulfide>methyl>phosphonate 
• 16215-12-6 (E)-1-chloro-4-(styrylsulfonyl)benzene 
• 1854-83-7 α-(4-Chlor-benzol-sulfonyl)-styrol 

Downstream Products

• 6031-02-3 2-phenylhexane 

Relevant articles and documents

Conjugate Addition Reactions of α,β-Unsaturated Ketones with Higher Order, Mixed Organocuprate Reagents, R2Cu(CN)Li2

Conjugate reactions of mixed cuprates R2Cu(CN)Li2 with α,β-unsaturated ketones are reported.These reagents, in most cases, react extremely rapidly affording the corresponding alkylated ketones in high yields.Attempts at trapping the intermediate enolates appeared to be successful using MeI as electrophile; however, the method is not general and was, therefore, not pursued.The effects of solvent and ligand composition on R2Cu(CN)Li2 as well as on the more highly mixed species RTRRCu(CN)Li2 have been examined.The selectivity of ligand transfer in these latter,second generation organocuprates is also discussed.