40596-10-9Relevant articles and documents
Samarium(II)-mediated reaction of allylic phosphate esters with carbonyl compounds: A new method for "Umpolung" of allylic phosphates
Araki, Shuki,Hatano, Masahiro,Ito, Hirokazu,Butsugan, Yasuo
, p. 329 - 336 (1987)
Allylic phosphates allylate ketones and aldehydes in the presence of samarium(II) iodide.The coupling proceeds with the preservation of the olefin geometry ever, regio- and stereoselectivity are not high.