Samarium(II)-mediated reaction of allylic phosphate esters with carbonyl compounds: A new method for "Umpolung" of allylic phosphates

DOI: 10.1016/S0022-328X(00)99810-3

Source and publish data:

Journal of Organometallic Chemistry p. 329 - 336 (1987)

Update date:2022-09-26

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Authors:

Araki, Shuki

Hatano, Masahiro

Ito, Hirokazu

Butsugan, Yasuo

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Article abstract of DOI:10.1016/S0022-328X(00)99810-3

Allylic phosphates allylate ketones and aldehydes in the presence of samarium(II) iodide.The coupling proceeds with the preservation of the olefin geometry ever, regio- and stereoselectivity are not high.

Full text of DOI:10.1016/S0022-328X(00)99810-3

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