Samarium(II)-mediated reaction of allylic phosphate esters with carbonyl compounds: A new method for "Umpolung" of allylic phosphates

DOI: 10.1016/S0022-328X(00)99810-3

Source and publish data:

Journal of Organometallic Chemistry p. 329 - 336 (1987)

Update date:2022-09-26

Topics:

Authors:

Araki, Shuki

Hatano, Masahiro

Ito, Hirokazu

Butsugan, Yasuo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)99810-3

Allylic phosphates allylate ketones and aldehydes in the presence of samarium(II) iodide.The coupling proceeds with the preservation of the olefin geometry ever, regio- and stereoselectivity are not high.

Full text of DOI:10.1016/S0022-328X(00)99810-3

Products guided by the article

Product name:3-phenyl-4-propyl-1-hepten-4-ol

Cas No:40596-10-9

R&D Labs maybe for 40596-10-9

Liaoyang hengye Chemical Co., Ltd.

Contact:86-419-5850866

Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-5161 3915

Address:Shanghai YangPu
Kaymossy BioChem Tech Co., Ltd

website:http://www.kaimosi.com

Contact:0571-87191913/0571-87199097

Address:Room 215, Building 3rd, No.288 Ningxia Road, Qingdao city, China
Josun International Limited

website:http://www.josunpharma.com

Contact:+86-311-80715268 80766839

Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China
Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China

Relevant to this article

π-Stacking Conversion and Enhanced Force-Stimuli Response of a Divinylanthracene Derivative in a Hydrogen-Bonded Framework

Doi:10.1021/acs.cgd.0c01637
(2021)
Highly efficient [2 + 2] intramolecular cyclizations of allenynes under microwave irradiation: Construction of fused bicyclic compounds

Doi:10.1039/b508306k
(2005)
Thiol Acidities and Thiolate Ion Reactivities toward Butyl Chloride in Dimethyl Sulfoxide Solution. The Question of Curvature in Broensted Plots

Doi:10.1021/jo00138a005
(1982)
Catalytic and direct methyl sulfonylation of alkenes and alkynes using a methyl sulfonyl radical generated from a DMSO, dioxygen and copper system

Doi:10.1039/c4sc01901f
(2014)
On the reaction of beta-mercaptopropionic acid, beta-diethylaminoethylmercaptan and cysteine with various isothiocyanates

Doi:10.1002/hlca.19650480622
(1965)
Doi:10.1021/ja00888a032
(1963)

Article Doi