406502-78-1

Basic information

• Product Name: dimethyl (S_S,2S,3R)-(-)-N-(p-toluenesulfinyl)-3-phenylaziridine-2-phosphonate
• Synonyms: dimethyl (S_S,2S,3R)-(-)-N-(p-toluenesulfinyl)-3-phenylaziridine-2-phosphonate
• CAS NO: 406502-78-1
• Molecular Weight: 365.39
• Mol File: 406502-78-1.mol

Chemical Properties

• CAS DataBase Reference: dimethyl (S_S,2S,3R)-(-)-N-(p-toluenesulfinyl)-3-phenylaziridine-2-phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl (S_S,2S,3R)-(-)-N-(p-toluenesulfinyl)-3-phenylaziridine-2-phosphonate(406502-78-1)
• EPA Substance Registry System: dimethyl (S_S,2S,3R)-(-)-N-(p-toluenesulfinyl)-3-phenylaziridine-2-phosphonate(406502-78-1)

Safety Data

• Hazardous Substances Data: 406502-78-1(Hazardous Substances Data)

Upstream product

• 350479-90-2 (S,E)-N-benzylidene-4-methylbenzenesulfinamide 

Downstream Products

• 406502-83-8 dimethyl (2R)-(+)-2-phenyl-2H-azirine 3-phosphonate 
• 406502-80-5 dimethyl (2S,3R)-(-)-3-phenylaziridine-2-phosphonate 

Relevant articles and documents

2H-Azirine 3-phosphonates: a new class of chiral iminodienophiles. Asymmetric synthesis of quaternary piperidine phosphonates.

[reaction: see text] Diels-Alder reactions of enantiomerically enriched 2H-azirine 3-phosphonates and dienes stereoselectively furnish optically pure, bicyclic aziridine adducts that on hydrogenation afford the first examples of enantiopure quaternary pip