406502-80-5Relevant articles and documents
Photodesulfinylation of optically active N-sulfinyl amines
Davis, Franklin A.,Ramachandar, Tokala,Zhang, Yanfeng,Chai, Jing,Qiu, Hui,Deng, Jianghe,Velvadapu, Venkata
experimental part, p. 4042 - 4044 (2010/08/07)
Photolysis of enantiopure N-sulfinyl amines (sulfinamides) in Et2O-MeOH gives amines in good yield without racemization.
Asymmetric synthesis of aziridine 2-phosphonates from enantiopure sulfinimines (N-sulfinyl imines). Synthesis of α-amino phosphonates
Davis, Franklin A.,Wu, Yongzhong,Yan, Hongxing,McCoull, William,Prasad, Kavirayani R.
, p. 2410 - 2419 (2007/10/03)
An aza-Darzens reaction, involving the addition of chloromethylphosphonate anions to enantiopure sulfinimines, has been developed for the asymmetric synthesis of aziridine 2-phosphonates. Best results involve cyclization of the syn and anti diastereomeric
2H-Azirine 3-phosphonates: a new class of chiral iminodienophiles. Asymmetric synthesis of quaternary piperidine phosphonates.
Davis, Franklin A,Wu, Yongzhong,Yan, Hongxing,Prasad, Kavirayani R,McCoull, William
, p. 655 - 658 (2007/10/03)
[reaction: see text] Diels-Alder reactions of enantiomerically enriched 2H-azirine 3-phosphonates and dienes stereoselectively furnish optically pure, bicyclic aziridine adducts that on hydrogenation afford the first examples of enantiopure quaternary pip