406721-01-5Relevant academic research and scientific papers
Triphenylphosphine-mediated reduction of electron-deficient propargyl ethers to the allylic ethers
Tsai, Ming-Shan,Rao, U. Narasimha,Wang, Jeng-Rong,Liang, Chung-Hao,Yeh, Ming-Chang P.
, p. 869 - 876 (2007/10/03)
Semihydrogenation of α,β-unsaturated ynoates and -ynones bearing a γ-alkoxy group can be performed using triphenylphosphine and water. α,β-Unsaturated ynoates were reduced to a mixture of cis and trans α,β-unsaturated enoates, whereas, ynones were reduced to trans α,β-unsaturated enones as the only products.
