407-95-4Relevant articles and documents
Ionic liquids as media for nucleophilic flurination
Murray, Christopher B.,Sandford, Graham,Korn, Stewart R.
, p. 81 - 84 (2007/10/03)
The use of Room Temperature Ionic Liquids (RTILs) for a variety of halogen exchange (Halex) fluorination processes using alkali metal fluorides is assessed. Whilst fluorination of a range of halogenated substrates is possible in good yield, the utility of RTILs as reusable, inert media for such reactions is limited by the gradual decomposition of the RTIL in the presence of highly basic fluoride ion.
Cocatalysis by tetravalent tin compounds in phase-transfer catalyzed fluorination of alkyl halides and sulfonates
Ma?kosza, Mieczys?aw,Bujok, Robert
, p. 2761 - 2763 (2007/10/03)
Phase-transfer catalyzed fluorination of alkyl halides or sulfonates is co-catalyzed efficiently by triorganotin halides. The cocatalytic action is due to continuous formation of lipophilic hypervalent triorganodifluorostannate anions, which act as fluori
Hydrated tetrabutylammonium fluoride as a powerful nucleophilic fluorinating agent
Albanese, Domenico,Landini, Dario,Penso, Michele
, p. 9587 - 9589 (2007/10/03)
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