36049-78-2

Basic information

• Product Name: rac-(2R*)-2-Iodooctane
• Synonyms: rac-(2R*)-2-Iodooctane
• CAS NO: 36049-78-2
• Molecular Formula: C₈H₁₇I
• Molecular Weight: 240.12505
• Mol File: 36049-78-2.mol
• Article Data: 36

Chemical Properties

• Melting Point: -45.7°C (estimate)
• Boiling Point: 212.38°C (estimate)
• Appearance: /
• Density: 1.3251
• Refractive Index: 1.4896
• CAS DataBase Reference: rac-(2R*)-2-Iodooctane(CAS DataBase Reference)
• NIST Chemistry Reference: rac-(2R*)-2-Iodooctane(36049-78-2)
• EPA Substance Registry System: rac-(2R*)-2-Iodooctane(36049-78-2)

Safety Data

• Hazardous Substances Data: 36049-78-2(Hazardous Substances Data)

Upstream product

• 4128-31-8 rac-octan-2-ol 
• 628-61-5 2-chlorooctane 
• 557-35-7 2-bromooctane 
• 24848-81-5 B(O-2-C₈H₁₇)3 
• 10034-85-2 hydrogen iodide 
• 1809-13-8 phosphonic acid bis-((S)-1-methyl-heptyl) ester 
• 6169-06-8 (+)-octan-2-ol 
• 629-05-0 n-octyne 
• 463-11-6 1-Fluoro-octane 
• 924-80-1 2-octyl mesylate 
• 5978-70-1 (R)-Octan-2-ol 
• 1028-12-2 2-Octyl tosylate 
• 111-66-0 oct-1-ene 
• 13389-42-9 trans-2-Octene 

Downstream Products

• 2570-96-9 2-octyl cyanide 
• 111-65-9 octane 
• 407-95-4 2-fluorooctane 
• 111-66-0 oct-1-ene 
• 44855-57-4 rac-2-aminooctane 
• 111-67-1 2-octene 
• 52230-95-2 4-methoxymethyl-2-(2-methyl-octyl)-5-phenyl-4,5-dihydro-oxazole 
• 70116-81-3 2,4,6-trimethyl-benzoic acid-(1-methyl-heptyl ester) 
• 65500-65-4 (1-methyl-heptyl)-hydrazine 
• 74112-36-0 2-Octyl acetate 
• 111-13-7 hexyl-methyl-ketone 
• 111-87-5 octanol 
• 4128-31-8 rac-octan-2-ol 
• 69442-38-2 1-methylheptyl m-chlorobenzoate 

Relevant articles and documents

A comparative kinetic study of nucleophilic substitution under PTC conditions in liquid-liquid and solid-liquid systems

The phenomenon of initial exponential burst (IB) on kinetic curves in the reaction with solid salts was observed in the study on the S(N)2 substitution reaction of 2-octylmesylate with potassium halides under phase- transfer catalysis (PTC) conditions in liquid-liquid (l/l) and solid-liquid (s/l) systems. The mechanistic scheme describing the IB phenomenon in application to s/l PTC has been developed from the analysis of IB kinetic model known in enzyme kinetics.

STRUCTURAL INCREMENTS OF 13C NMR CHEMICAL SHIFTS IN MONOIODOALKANES

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Iron-Catalyzed Oxyalkylation of Terminal Alkynes with Alkyl Iodides

A general oxyalkylation of terminal alkynes enabled by iron catalysis has been developed. Primary and secondary alkyl iodides acted as the alkylating reagents and afforded a range of α-alkylated ketones under mild reaction conditions. Acetyl tert-butyl peroxide (TBPA) was used as the radical relay precursor, providing the initiated methyl radical to start the radical relay process. Preliminary mechanistic studies were conducted, and late-stage functionalizations of natural product derivatives were performed.

Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of Iodoalkanes

The preparation of anhydrous hydrogen iodide directly from molecular hydrogen and iodine using a rhodium catalyst is reported for the first time. The anhydrous hydrogen iodide generated was proven to be highly active in the transformations of alkenes, phenyl aldehydes, alcohols, and cyclic ethers to the corresponding iodoalkanes. Therefore, the present methodology not only has provided convenient access to anhydrous hydrogen iodide but also offers a practical preparation method for various iodoalkanes in excellent atom economy.