4070-53-5

Basic information

• Product Name: Benzamide, 3-chloro-N-hydroxy-
• CAS NO: 4070-53-5
• Molecular Formula: C7H6ClNO2
• Molecular Weight: 171.583
• Mol File: 4070-53-5.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzamide, 3-chloro-N-hydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 3-chloro-N-hydroxy-(4070-53-5)
• EPA Substance Registry System: Benzamide, 3-chloro-N-hydroxy-(4070-53-5)

Safety Data

• Hazardous Substances Data: 4070-53-5(Hazardous Substances Data)

Upstream product

• 34158-71-9 3-chlorobenzaldehyde oxime 
• 618-46-2 m-Chlorobenzoyl chloride 
• 587-04-2 m-Chlorobenzaldehyde 
• 66134-68-7 N-(3-Chlorbenzoyloxy)-succinimid 
• 535-80-8 3-chlorobenzoate 
• 1128-76-3 3-chloro-benzoic acid ethyl ester 
• 2905-65-9 methyl 3-chlorobenzoate 

Downstream Products

• 57000-63-2 2-(3-chlorophenyl)-5-phenyloxazole 
• 13208-31-6 N_.N'-Di-(m-chlor-phenyl)-harnstoff 
• 139-71-9 m-chloroformanilide 
• 414897-78-2 1-(tert-butyl)-3-(3-chlorophenyl)urea 
• 1394836-93-1 5-chloro-1-(3-chlorobenzoyl)benzo[c]isoxazol-3(1H)-one 

Relevant articles and documents

Cu(II)-Catalyzed C-H Amidation/Cyclization of Azomethine Imines with Dioxazolones via Acyl Nitrenes: A Direct Access to Diverse 1,2,4-Triazole Derivatives

We report a Cu(II)-catalyzed C-H amidation/cyclization of azomethine imines with dioxazolones as acyl nitrene transfer reagents under additive-and ligand-free conditions. An array of 1,2,4-triazolo[1,5-a]pyridine derivatives were afforded in moderate to good yields with excellent functional group tolerance. In addition, scale-up reaction and photoluminescence properties were discussed.

Synthesis of sulfimides and N-Allyl-N-(thio)amides by Ru(II)catalyzed nitrene transfer reactions of N-acyloxyamides

The N-acyloxyamides were employed as effective N-acyl nitrene precursors in reactions with thioethers under the catalysis of a commercially available Ru(II) complex, from which a variety of sulfimides were synthesized efficiently and mildly. If an allyl group is contained in the thioether precursor, the [2,3]-sigmatropic rearrangement of the sulfimide occurs simultaneously and the N-allyl-N-(thio)amides were obtained as the final products. Preliminary mechanistic studies indicated that the Ru-nitrenoid species should be a key intermediate in the transformation.

Rhodium(III)-catalyzed C4-amidation of indole-oximes with dioxazolones: Via C-H activation

A novel method for the Rh(III)-catalyzed oxime-directed C-H amidation of indoles with dioxazolones has been developed. This strategy provides an exclusive site selectivity and the directing group can be easily removed. This transformation features a wide substrate scope, good functional group tolerance and excellent yields, and may serve as a significant tool to construct structurally diverse indole derivatives for the screening of potential pharmaceuticals in the future. This journal is