40754-58-3Relevant academic research and scientific papers
Thia-Diels–Alder reactions of hetaryl thioketones with nonactivated 1,3-dienes leading to 3,6-dihydro-2H-pyrans: evidence for a diradical mechanism
Mlostoń, Grzegorz,Grzelak, Paulina,Linden, Anthony,Heimgartner, Heinz
, p. 518 - 525 (2017/08/30)
[Figure not available: see fulltext.] Dihetaryl thioketones possessing thiophen-2-yl and selenophen-2-yl rings react as “superdienophilic” reagents with nonactivated 1,3-dienes such as 2,3-dimethylbuta-1,3-diene, cyclopentadiene, and mixtures of isomeric
Die dienophile reaktivitaet der C = S-bindung in (4 + 2)-cycloadditionen: Kinetische Studie mit thiobenzophenonen und thiofluorenon
Schatz, Juergen,Sauer, Juergen
, p. 4767 - 4770 (2007/10/02)
Thiobenzophenone (1a) and thiofluorenone (2) show high dienophilic reactivity as kinetic measurements demonstrate for a larger number of dienes.
Preparation and Cycloaddition Chemistry of Thio- and Selenocarbonyls Derived from Reaction of Elemental Sulfur and Selenium with Stabilized α-Halo Anions
Abelman, Matthew M.
, p. 7389 - 7392 (2007/10/02)
Reaction of diethyl chloromalonate with Cs2CO3 in the presence of elemental S8 or Sen generates the corresponding diethyl thioxo- or selenoxomalonates which are subsequently trapped in situ with various 1,3-dienes.Similarly, the chalcogen carbonyls can be prepared from other halogenated compounds using DBU as the base and effectively trapped in Diels-Alder fashion with 2,3-dimethyl-1,3-butadiene (Table 2).
