40891-99-4Relevant articles and documents
SYNTHESIS OF PERFLUOROETHERS BY LIQUID PHASE FLUORINATION
Modena, Silvana,Calini, Pierangelo,Gregorio, Guglielmo,Moggi, Giovanni
, p. 349 - 358 (1988)
Liquid phase fluorination of diethyleneglycol dimethyl ether, tetraethyleneglycol dimethyl ether, 2 tetrahydrofuran and 2 dioxane 1,4 produce the corresponding perfluoroethers in 56, 43, 67 and 74 percent yields respectively.The by-products are partially fluorinated compounds and no fragmentation is observed.The simplicity of the reactions and method of preparation make this approach to fluorinated fluids and oils industrially attractive.
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Adcock,J.L.,Cherry,M.L.
, p. 343 (1985)
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Gerhardt,G.E.,Lagow,R.J.
, p. 259 - 260 (1977)