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Product FOB Price Min.Order Supply Ability Supplier
2-Methoxyethyl ether 111-96-6 /manufacturer/low price/high quality/in stock
Cas No: 111-96-6
No Data 1 Gram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
Diethylene glycol dimethyl ether
Cas No: 111-96-6
No Data 1 Kilogram Metric Ton/Day Wuhan Shengmao Corp Contact Supplier
2-Methoxyethyl ether; Diethylene glycol dimethyl ether
Cas No: 111-96-6
USD $ 1.0-3.0 / Kilogram 1 Kilogram 10 Kilogram/Day Hebei yanxi chemical co.,LTD. Contact Supplier
High quality diethylene glycol dimethyl ether (reach) supplier in China
Cas No: 111-96-6
No Data 1 Kilogram 6000 Metric Ton/Year Simagchem Corporation Contact Supplier
Factory supply Diethylene Glycol Dimethyl Ether Cas 111-96-6 with favorable price
Cas No: 111-96-6
USD $ 3.5-4.0 / Kilogram 190 Kilogram 800 Metric Ton/Year Wuhan Fortuna Chemical Co.,Ltd Contact Supplier
Diethyleneglycol dimethyl ether
Cas No: 111-96-6
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Bis(2-methoxy ethyl)ether
Cas No: 111-96-6
USD $ 1.0-1.0 / Metric Ton 3 Metric Ton 50 Metric Ton/Day Henan Sinotech Import&Export Corporation Contact Supplier
diglyme/high quality/best price
Cas No: 111-96-6
No Data 10 Gram 200 Kilogram/Month Hubei Jusheng Technology Co., Ltd., Contact Supplier
2-Methoxyethyl ether
Cas No: 111-96-6
No Data 1 Kilogram 200 Kilogram/Month HENAN SUNLAKE ENTERPRISE CORPORATION Contact Supplier
Diethylene Glycol Dimethyl Ether cas111-96-6 DEDMfactory supplier manufacturer
Cas No: 111-96-6
No Data No Data 1000 Metric Ton/Month Crovell Biotech (Hebei) Co., Ltd. Contact Supplier

111-96-6 Usage

Health Hazard

INGESTION (severe cases): nausea, vomiting, abdominal cramps, weakness progressing to coma.

Reactivity Profile

A violent explosion occurred when lithium aluminum hydride was being used to dry 2-Methoxyethyl ether. The ignition may have occurred due to the presence of large amounts of water or perhaps peroxide formed in the ether. About 75% of the ether had been removed when the explosion occurred, [MCA Case History 1494 (1968)].

Uses

Solvent; it is used as reaction medium for Grignard and similar synthesis.

Air & Water Reactions

Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously, [MCA Case History 616(1960)]. Water soluble.

Fire Hazard

2-Methoxyethyl ether is combustible.

Definition

ChEBI: A polyether that is the dimethyl ether derivative of diethylene glycol.

Purification Methods

Dry diglyme with NaOH pellets or CaH2, then reflux with, and distil (under reduced pressure) it from Na, CaH2, LiAlH4, NaBH4 or NaH. These operations are carried out under N2. The amine-like odour of diglyme has been removed by shaking with a weakly acidic ion-exchange resin (Amberlite IR-120) before drying and distilling. Addition of 0.01% NaBH4 to the distillate inhibits peroxidation. Purify it also as for dioxane. It has been passed through a 12-in column of molecular sieves to remove water and peroxides. [Beilstein 1 IV 2393.]

Uses

Solvent; reaction medium for Grignard and similar syntheses.

Chemical Properties

Colorless clear liquid

General Description

Colorless watery liquid with a pleasant odor. Floats and mixes with water.
InChI:InChI:1S/C6H14O3/c1-7-3-5-9-6-4-8-2/h3-6H2,1-2H3

111-96-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (32210)  Diethyleneglycoldimethylether  puriss. p.a., ≥99.5% (GC) 111-96-6 32210-1L 3,348.54CNY Detail
Sigma-Aldrich (M14102)  Diethyleneglycoldimethylether  ReagentPlus®, 99% 111-96-6 M14102-20L 11,547.90CNY Detail
Sigma-Aldrich (M14102)  Diethyleneglycoldimethylether  ReagentPlus®, 99% 111-96-6 M14102-2.5L 2,160.99CNY Detail
Sigma-Aldrich (M14102)  Diethyleneglycoldimethylether  ReagentPlus®, 99% 111-96-6 M14102-1L 1,407.51CNY Detail
Sigma-Aldrich (M14102)  Diethyleneglycoldimethylether  ReagentPlus®, 99% 111-96-6 M14102-500ML 1,041.30CNY Detail
Vetec (V900237)  Diethyleneglycoldimethylether  Vetec reagent grade, 98% 111-96-6 V900237-500ML 101.23CNY Detail
Sigma-Aldrich (256390)  Diethyleneglycoldimethylether  spectrophotometric grade, ≥99% 111-96-6 256390-2L 3,671.46CNY Detail
Sigma-Aldrich (256390)  Diethyleneglycoldimethylether  spectrophotometric grade, ≥99% 111-96-6 256390-1L 2,523.69CNY Detail
Sigma-Aldrich (281662)  Diethyleneglycoldimethylether  anhydrous, 99.5% 111-96-6 281662-2L 3,823.56CNY Detail
Sigma-Aldrich (281662)  Diethyleneglycoldimethylether  anhydrous, 99.5% 111-96-6 281662-1L 2,699.19CNY Detail
Sigma-Aldrich (281662)  Diethyleneglycoldimethylether  anhydrous, 99.5% 111-96-6 281662-100ML 1,325.61CNY Detail
Sigma-Aldrich (04143)  Diethyleneglycoldimethylether  analytical standard 111-96-6 04143-5ML-F 993.33CNY Detail

111-96-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name diglyme

1.2 Other means of identification

Product number -
Other names diethyleneglycol dimethylether

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Processing aids, not otherwise listed
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:111-96-6 SDS

111-96-6Related news

Raman spectra of perdeuterated ethylene glycol dimethyl ether and Diethylene Glycol Dimethyl Ether (cas 111-96-6) and the molecular force field of oxyethylene compounds08/23/2019

Raman spectra of ethylene glycol dimethyl ether-d10 and diethylene glycol dimethyl ether-d14 were measured in the liquid and solid states, and spectral analysis was made on the basis of normal-coordinate treatment. The previous force field for the oxyethylene group was refined in the light of th...detailed

Radiation-chemical transformations of Diethylene Glycol Dimethyl Ether (cas 111-96-6) at room temperature and at boiling point08/20/2019

Diethylene glycol dimethyl ether (diglyme) is interesting as a representative of ethers with several oxygen bridges in the molecule and as a model alternative fuel. A comparative study of the diglyme radiolysis at room temperature and at the boiling point was carried out. Boiling facilitates the...detailed

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