40906-92-1Relevant academic research and scientific papers
The Preparation of Some Octenyl Sulfides from Oct-1-en-3-ol and Oct-2-en-1-ol
Binns, Malcolm R.,Haynes, Richard K.,Lambert, Dale E.,Schober, Paul A.,Turner, Susan G.
, p. 281 - 290 (2007/10/02)
(E)- and (Z)-1-(Phenylthio)oct-2-ene, (E)-1-(methylthio)- and 1-(t-butylthio)-oct-2-ene, S- N,N-dimethylthiocarbamate, S- N,N-dimethylthiocarbamate, (E)-(oct-2-enylthio)benzothiazole, and S- N,N,N',N'-tetramethylphosphorodiamidothioate have been prepared by nucleophilic substitution reactions and - and -sigmatropic shifts involving intermediates prepared from oct-1-en-3-ol and (E)- and (Z)-oct-2-en-1-ol.
REGIOSPECIFIC ALLYLATION OF SULFUR SUBSTITUTED ACTIVE METHYLENE COMPOUNDS WITH ALLYLIC BROMIDES
Ono, Noboru,Miyake, Hideyoshi,Tanabe, Yo,Tanaka, Kazuhiko,Kaji, Aritsune
, p. 1365 - 1368 (2007/10/02)
Allylation of sulfur substituted active methylene compounds such as RSCH2Y with allylic bromides in the presence of bases gives a mixture of the SN2-product and the apparent SN2'-product.The former product is selectively obtained in alkylation in a nonpolar solvent.Synthetic utility of this regiospecific allylation is demonstrated in the simple synthesis of pellitorine.
