409102-38-1Relevant academic research and scientific papers
Dihedral angle restriction within a peptide-based tertiary alcohol kinetic resolution catalyst
Angione, Mary C.,Miller, Scott J.
, p. 5254 - 5261 (2006)
Kinetic resolution of several tertiary alcohols has been evaluated with a peptide-based catalyst that was designed to probe the role of dihedral angle restrictions for certain bonds within the catalyst. In particular, the nucleophilic residue (π-Me)-His h
Asymmetric azidation-cycloaddition with open-chain peptide-based catalysts. A sequential enantioselective route to triazoles
Guerin, David J.,Miller, Scott J.
, p. 2134 - 2136 (2007/10/03)
A family of β-substituted histidine-containing peptides has been synthesized to probe the effect of noncovalent conformational rigidification on catalyst enantioselectivity. Unambiguous enhancement of enantioselectivity in the conjugate addition of azide
