40933-56-0

Upstream product

• 70372-58-6 2-bromo-2-fluoro-1-phenylcyclopropane 
• 127-09-3 sodium acetate 
• 16084-65-4 2-chloro-2-fluoro-1-phenylcyclopropane 
• 826-08-4 2-Fluor-3t-phenyl-allylalkohol 
• 100-52-7 benzaldehyde 
• 350-99-2 ethyl (E/Z)-2-fluoro-3-phenylprop-2-enoate 
• 826-08-4 2-fluoro 3-phenyl prop-2-ene 1-ol (Z) 

Relevant academic research and scientific papers

Palladium-Catalyzed Allyl-Allyl Reductive Coupling of Allylamines or Allylic Alcohols with H2as Sole Reductant

Catalytic carbon-carbon bond formation building on reductive coupling is a powerful method for the preparation of organic compounds. The identification of environmentally benign reductants is key for establishing an efficient reductive coupling reaction. Herein an efficient strategy enabling H2 as the sole reductant for the palladium-catalyzed allyl-allyl reductive coupling reaction is described. A wide range of allylamines and allylic alcohols as well as allylic ethers proceed smoothly to deliver the C-C coupling products under 1 atm of H2. Kinetic studies suggested that the dinuclear palladium species was involved in the catalytic cycle.

Copper(I)-catalyzed solvolysis of gem-chlorofluoro- and gem-bromofluorocyclopropanes. Preparation of 2-fluoroallylic ethers, esters and alcohols

Copper(I)-catalyzed solvolysis of gem-chlorofluoro- and gem-bromofluorocyclopropanes in MeOH, NaOAc/AcOH, NaOAc/DMF, HCO2Na/HCO2H or water/dioxane affords 2-fluoroallylic ethers, esters or alcohols in moderate to excellent yields. Th